Copper polytellurite-chlorides with A2 + cations ([Formula presented], Pb) obtained by CVT reactions

Diana O. Zinyakhina, Oleg I. Siidra, Dmitri O. Charkin, Evgeniy V. Nazarchuk, Rimma S. Bubnova

Результат исследований: Научные публикации в периодических изданияхстатья

2 Цитирования (Scopus)

Выдержка

Two novel polytellurite-chlorides Pb5Cu2(Te4O11)Cl8 (1) and CdCu2(Te3O8)Cl2 (2) were obtained by a chemical vapor transport (CVT-reactions) reactions. The structure of 1 is based on [Pb5Cu2(Te4O11)]8 + one-dimensional blocks with full and partially occupied Cl sites around. The structure of 2 can be described as being formed by two types of one-dimensional units formed by Cd,Cu-centered polyhedra and TeO3, TeO4 pyramids sharing via common O atoms into electroneutral [CdCu2(Te3O8)Cl2]0 sheets. Obtaining of novel polytellurite-chlorides demonstrates effectiveness of CVT techniques for preparation of different tellurite-based complex layered materials.

Язык оригиналаанглийский
Страницы (с-по)94-97
Число страниц4
ЖурналInorganic Chemistry Communications
Том71
DOI
СостояниеОпубликовано - 1 сен 2016

Отпечаток

copper chlorides
Cations
Chlorides
Copper
Positive ions
chlorides
cations
pyramids
polyhedrons
Vapors
vapors
Atoms
preparation
atoms
tellurous acid

Предметные области Scopus

  • Физическая и теоретическая химия
  • Неорганическая химия
  • Химия материалов

Цитировать

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title = "Copper polytellurite-chlorides with A2 + cations ([Formula presented], Pb) obtained by CVT reactions",
abstract = "Two novel polytellurite-chlorides Pb5Cu2(Te4O11)Cl8 (1) and CdCu2(Te3O8)Cl2 (2) were obtained by a chemical vapor transport (CVT-reactions) reactions. The structure of 1 is based on [Pb5Cu2(Te4O11)]8 + one-dimensional blocks with full and partially occupied Cl sites around. The structure of 2 can be described as being formed by two types of one-dimensional units formed by Cd,Cu-centered polyhedra and TeO3, TeO4 pyramids sharing via common O atoms into electroneutral [CdCu2(Te3O8)Cl2]0 sheets. Obtaining of novel polytellurite-chlorides demonstrates effectiveness of CVT techniques for preparation of different tellurite-based complex layered materials.",
keywords = "Copper, CVT-reactions, Lone-pair, Polytellurites, Single crystal X-ray diffraction, Tellurium",
author = "Zinyakhina, {Diana O.} and Siidra, {Oleg I.} and Charkin, {Dmitri O.} and Nazarchuk, {Evgeniy V.} and Bubnova, {Rimma S.}",
year = "2016",
month = "9",
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doi = "10.1016/j.inoche.2016.07.007",
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journal = "Inorganic Chemistry Communication",
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Copper polytellurite-chlorides with A2 + cations ([Formula presented], Pb) obtained by CVT reactions. / Zinyakhina, Diana O.; Siidra, Oleg I.; Charkin, Dmitri O.; Nazarchuk, Evgeniy V.; Bubnova, Rimma S.

В: Inorganic Chemistry Communications, Том 71, 01.09.2016, стр. 94-97.

Результат исследований: Научные публикации в периодических изданияхстатья

TY - JOUR

T1 - Copper polytellurite-chlorides with A2 + cations ([Formula presented], Pb) obtained by CVT reactions

AU - Zinyakhina, Diana O.

AU - Siidra, Oleg I.

AU - Charkin, Dmitri O.

AU - Nazarchuk, Evgeniy V.

AU - Bubnova, Rimma S.

PY - 2016/9/1

Y1 - 2016/9/1

N2 - Two novel polytellurite-chlorides Pb5Cu2(Te4O11)Cl8 (1) and CdCu2(Te3O8)Cl2 (2) were obtained by a chemical vapor transport (CVT-reactions) reactions. The structure of 1 is based on [Pb5Cu2(Te4O11)]8 + one-dimensional blocks with full and partially occupied Cl sites around. The structure of 2 can be described as being formed by two types of one-dimensional units formed by Cd,Cu-centered polyhedra and TeO3, TeO4 pyramids sharing via common O atoms into electroneutral [CdCu2(Te3O8)Cl2]0 sheets. Obtaining of novel polytellurite-chlorides demonstrates effectiveness of CVT techniques for preparation of different tellurite-based complex layered materials.

AB - Two novel polytellurite-chlorides Pb5Cu2(Te4O11)Cl8 (1) and CdCu2(Te3O8)Cl2 (2) were obtained by a chemical vapor transport (CVT-reactions) reactions. The structure of 1 is based on [Pb5Cu2(Te4O11)]8 + one-dimensional blocks with full and partially occupied Cl sites around. The structure of 2 can be described as being formed by two types of one-dimensional units formed by Cd,Cu-centered polyhedra and TeO3, TeO4 pyramids sharing via common O atoms into electroneutral [CdCu2(Te3O8)Cl2]0 sheets. Obtaining of novel polytellurite-chlorides demonstrates effectiveness of CVT techniques for preparation of different tellurite-based complex layered materials.

KW - Copper

KW - CVT-reactions

KW - Lone-pair

KW - Polytellurites

KW - Single crystal X-ray diffraction

KW - Tellurium

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