TY - JOUR
T1 - Concentration effect on photoluminescence of Eu3+-doped nanocrystalline YVO4
AU - Kolesnikov, I.E.
AU - Tolstikova, D.V.
AU - Kurochkin, A.V.
AU - Pulkin, S.A.
AU - Manshina, A.A.
AU - Mikhailov, M.D.
PY - 2015
Y1 - 2015
N2 - Eu3+-doped YVO4 nanopowders were prepared by the modified Pechini method. The structural properties were studied with XRD, SEM and Raman spectroscopy. XRD pattern indicates that nanocrystalline YVO4:Eu3+ powders form only pure tetragonal phase. SEM images show that synthesized samples are mixture of large, well-faceted particles and weakly agglomerated nanoparticles. The symmetry of luminescent centers local surrounding was discussed in terms of asymmetry coefficient. Dependence of luminescent intensity on Eu3+ doping concentration was studied at different excitation wavelengths. Lifetimes of 5D0 level were measured for all the synthesized nanopowders. Also the probabilities of radiative, nonradiative processes, and the radiative lifetimes were calculated.
AB - Eu3+-doped YVO4 nanopowders were prepared by the modified Pechini method. The structural properties were studied with XRD, SEM and Raman spectroscopy. XRD pattern indicates that nanocrystalline YVO4:Eu3+ powders form only pure tetragonal phase. SEM images show that synthesized samples are mixture of large, well-faceted particles and weakly agglomerated nanoparticles. The symmetry of luminescent centers local surrounding was discussed in terms of asymmetry coefficient. Dependence of luminescent intensity on Eu3+ doping concentration was studied at different excitation wavelengths. Lifetimes of 5D0 level were measured for all the synthesized nanopowders. Also the probabilities of radiative, nonradiative processes, and the radiative lifetimes were calculated.
U2 - 10.1016/j.jlumin.2014.10.024
DO - 10.1016/j.jlumin.2014.10.024
M3 - Article
VL - 158
SP - 469
EP - 473
JO - Journal of Luminescence
JF - Journal of Luminescence
SN - 0022-2313
ER -