c-X laser excitation spectrum of the Hg–Ar vdW complex

K Amano, K Ohmori, T Kurosawa, H Chiba, M Okunishi, K Ueda, Y Sato, AZ Devdariani, EE Nikitin

Результат исследований: Научные публикации в периодических изданияхстатьярецензирование


We have measured the c(upsilon'=0-8)-X(upsilon=0) laser excitation spectrum of the Hg-Ar van der Waals complex. This corresponds to the first observation of the bound Hg-rare-gas complex in the dark c state. In this measurement, we employ the sequence of two laser pulses; the complex is excited by the first one to the dark bound level in the c state and then successively excited by the second one to another bright state for the optical detection. The Birge-Sponer (BS) plot of the upsilon' progression is well fitted by a straight line, suggesting that the c-state potential curve of Hg-Ar is well approximated by the Morse function. The linear fitting of this BS plot gives the potential parameters for the c state. (C) 1998 American Institute of Physics.

Язык оригиналаАнглийский
Страницы (с-по)8110-8113
Число страниц4
ЖурналJournal of Chemical Physics
Номер выпуска19
СостояниеОпубликовано - 15 мая 1998