Bidentate phosphine oxides as ligands to form GaIII shell complexes. [Ga(CH2(P(O)Ph)2)3]3+: Synthesis, structural and spectroscopic study

E. V. Grachova, G. Linti, I. D. Protasova, S. P. Tunik

Результат исследований: Научные публикации в периодических изданияхстатья

2 Цитирования (Scopus)


The tri-cationic shell gallium complex [Ga(CH2(P(O)Ph) 2)3]3+ containing three neutral diphosphate oxide ligands has been synthesized and structurally characterized by using X-ray crystallography, mass spectrometry, and 1H, 13C, 31P, and 71Ga NMR spectroscopy. The ligands form three equivalent six-membered chelate cycles to give an idealized octahedral environment around the Ga3+ ion. This compound is the first example of a mononuclear homoleptic octahedral structure formed by neutral phosphine oxide ligands in the chemistry of the 13 group elements in the +3 oxidation state.

Язык оригиналаанглийский
Страницы (с-по)2294-2296
Число страниц3
ЖурналZeitschrift fur Anorganische und Allgemeine Chemie
Номер выпуска13-14
СостояниеОпубликовано - 1 ноя 2009


Предметные области Scopus

  • Неорганическая химия