Analysis of the aging processes of writing ink: Raman spectroscopy versus gas chromatography aspects

Nikolai M. Grechukha, Kseniya O. Gorshkova, Maxim S. Panov, Ilya I. Tumkin, Elizaveta O. Kirillova, Vladimir V. Lukianov, Natalia P. Kirillova, Vladimir A. Kochemirovsky

Результат исследований: Научные публикации в периодических изданияхстатьянаучнаярецензирование

6 Цитирования (Scopus)

Выдержка

This work is devoted to the extremely popular but poorly developed scientific and forensic problem of the estimation of the actual dates of inscriptions placed on paper and made by ballpoint pens. It is shown that the degradation of writing inks with time may be controlled via Raman spectroscopy and gas chromatography. The time intervals for the implementation of each of these methods were determined using the ratios of the Raman peak intensities as degradation characteristics rather than their absolute values. In turn, this eliminates the effect of the concentration of a dye. The mutual influence of the volatile components and dyes of writing inks was also investigated and the time interval within which such influence is critical was found. According to the obtained results, a new methodological scheme for determining the age of documents, which were created at least 40 months ago, was proposed.

Язык оригиналаанглийский
Номер статьи991
ЖурналApplied Sciences (Switzerland)
Том7
Номер выпуска10
DOI
СостояниеОпубликовано - 2017

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    Предметные области Scopus

    • Гидродинамика и трансферные процессы
    • Химия и технология процессов
    • Прикладные компьютерные науки
    • Технология (все)
    • Материаловедение (все)
    • Контрольно-измерительные инструменты

    Цитировать

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    title = "Analysis of the aging processes of writing ink: Raman spectroscopy versus gas chromatography aspects",
    abstract = "This work is devoted to the extremely popular but poorly developed scientific and forensic problem of the estimation of the actual dates of inscriptions placed on paper and made by ballpoint pens. It is shown that the degradation of writing inks with time may be controlled via Raman spectroscopy and gas chromatography. The time intervals for the implementation of each of these methods were determined using the ratios of the Raman peak intensities as degradation characteristics rather than their absolute values. In turn, this eliminates the effect of the concentration of a dye. The mutual influence of the volatile components and dyes of writing inks was also investigated and the time interval within which such influence is critical was found. According to the obtained results, a new methodological scheme for determining the age of documents, which were created at least 40 months ago, was proposed.",
    keywords = "Criminology, Dye, Gas chromatography, Pigment, Raman spectroscopy, Writing inks",
    author = "Grechukha, {Nikolai M.} and Gorshkova, {Kseniya O.} and Panov, {Maxim S.} and Tumkin, {Ilya I.} and Kirillova, {Elizaveta O.} and Lukianov, {Vladimir V.} and Kirillova, {Natalia P.} and Kochemirovsky, {Vladimir A.}",
    year = "2017",
    doi = "10.3390/app7100991",
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    journal = "Applied Sciences (Switzerland)",
    issn = "2076-3417",
    publisher = "MDPI AG",
    number = "10",

    }

    Analysis of the aging processes of writing ink: Raman spectroscopy versus gas chromatography aspects. / Grechukha, Nikolai M.; Gorshkova, Kseniya O.; Panov, Maxim S.; Tumkin, Ilya I.; Kirillova, Elizaveta O.; Lukianov, Vladimir V.; Kirillova, Natalia P.; Kochemirovsky, Vladimir A.

    В: Applied Sciences (Switzerland), Том 7, № 10, 991, 2017.

    Результат исследований: Научные публикации в периодических изданияхстатьянаучнаярецензирование

    TY - JOUR

    T1 - Analysis of the aging processes of writing ink: Raman spectroscopy versus gas chromatography aspects

    AU - Grechukha, Nikolai M.

    AU - Gorshkova, Kseniya O.

    AU - Panov, Maxim S.

    AU - Tumkin, Ilya I.

    AU - Kirillova, Elizaveta O.

    AU - Lukianov, Vladimir V.

    AU - Kirillova, Natalia P.

    AU - Kochemirovsky, Vladimir A.

    PY - 2017

    Y1 - 2017

    N2 - This work is devoted to the extremely popular but poorly developed scientific and forensic problem of the estimation of the actual dates of inscriptions placed on paper and made by ballpoint pens. It is shown that the degradation of writing inks with time may be controlled via Raman spectroscopy and gas chromatography. The time intervals for the implementation of each of these methods were determined using the ratios of the Raman peak intensities as degradation characteristics rather than their absolute values. In turn, this eliminates the effect of the concentration of a dye. The mutual influence of the volatile components and dyes of writing inks was also investigated and the time interval within which such influence is critical was found. According to the obtained results, a new methodological scheme for determining the age of documents, which were created at least 40 months ago, was proposed.

    AB - This work is devoted to the extremely popular but poorly developed scientific and forensic problem of the estimation of the actual dates of inscriptions placed on paper and made by ballpoint pens. It is shown that the degradation of writing inks with time may be controlled via Raman spectroscopy and gas chromatography. The time intervals for the implementation of each of these methods were determined using the ratios of the Raman peak intensities as degradation characteristics rather than their absolute values. In turn, this eliminates the effect of the concentration of a dye. The mutual influence of the volatile components and dyes of writing inks was also investigated and the time interval within which such influence is critical was found. According to the obtained results, a new methodological scheme for determining the age of documents, which were created at least 40 months ago, was proposed.

    KW - Criminology

    KW - Dye

    KW - Gas chromatography

    KW - Pigment

    KW - Raman spectroscopy

    KW - Writing inks

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