TY - JOUR

T1 - Alexkhomyakovite, K-6(Ca2Na)(CO3)(5)Cl center dot 6H(2)O, a new mineral from the Khibiny alkaline complex, Kola peninsula, Russia

AU - Pekov, Igor V.

AU - Zubkova, Natalia V.

AU - Yapaskurt, Vasiliy O.

AU - Lykova, Inna S.

AU - Chukanov, Nikita V.

AU - Belakovskiy, Dmitry I.

AU - Britvin, Sergey N.

AU - Turchkova, Anna G.

AU - Pushcharovsky, Dmitry Y.

PY - 2019/2/21

Y1 - 2019/2/21

N2 - The new mineral alexkhomyakovite K-6(Ca2Na)(CO3)(5)Cl center dot 6H(2)O (IMA2015-013) occurs in a peralkaline pegmatite at Mt. Koashva, Khibiny alkaline complex, Kola peninsula, Russia. It is a hydrothermal mineral associated with villiaumite, natrite, potassic feldspar, pectolite, sodalite, biotite, lamprophyllite, titanite, fluorapatite, wadeite, burbankite, rasvumite, djerfisherite, molybdenite and an incompletely characterized Na-Ca silicate. Alexkhomyakovite occurs as equant grains up to 0.2 mm, veinlets up to 3 cm long and up to 1 mm thick and fine-grained aggregates replacing delhayelite. Alexkhomyakovite is transparent to translucent, colourless, white or grey, with vitreous to greasy lustre. It is brittle, the Mohs hardness is ca. 3. No cleavage was observed, the fracture is uneven. D-meas = 2.25(1), D-calc = 2.196 g cm(-3). Alexkhomyakovite is optically uniaxial (-), omega = 1.543(2), epsilon = 1.476(2). The infrared spectrum is reported. The chemical composition [wt%, electron microprobe data, CO2 and H2O contents calculated for 5 (CO3) and 6 (H2O) per formula unit (pfu), respectively] is: Na2O 4.09, K2O 35.72, CaO 14.92, MnO 0.01, FeO 0.02, SO3 0.11, Cl 4.32, CO2 28.28, H2O 13.90, -O=Cl -0.98, total 100.39. The empirical formula calculated on the basis of 9 metal cations pfu is K5.90Ca2.07Na1.03(CO3)(5)(SO4)(0.01)O0.05Cl0.95 center dot 6H(2)O. The numbers of CO3 groups and H2O molecules are based on structure data. Alexkhomyakovite is hexagonal, P6(3)/mcm, a 9.2691(2), c 15.8419(4) angstrom, V 1178.72(5) angstrom(3) and Z = 2. The strongest reflections of the powder X-ray diffraction pattern [d angstrom(I)(hkl)] are: 7.96(27)(002), 3.486(35)(113), 3.011(100)(114), 2.977(32)(211), 2.676(36)(300), 2.626(42)(213, 115), 2.206(26)(311) and 1.982(17)(008). The crystal structure (solved from single-crystal X-ray diffraction data, R = 0.0578) is unique. It is based on (001) heteropolyhedral layers of pentagonal bipyramids (Ca,Na)O-5(H2O)(2) interconnected via carbonate groups of two types, edge-sharing ones and vertex-sharing ones. Ca and Na are disordered. Ten-fold coordinated K cations centre KO6Cl(H2O)(3) polyhedra on either side of the heteropolyhedral layer. A third type of carbonate group and Cl occupy the interlayer. The mineral is named in honour of the outstanding Russian mineralogist Alexander Petrovich Khomyakov (1933-2012).

AB - The new mineral alexkhomyakovite K-6(Ca2Na)(CO3)(5)Cl center dot 6H(2)O (IMA2015-013) occurs in a peralkaline pegmatite at Mt. Koashva, Khibiny alkaline complex, Kola peninsula, Russia. It is a hydrothermal mineral associated with villiaumite, natrite, potassic feldspar, pectolite, sodalite, biotite, lamprophyllite, titanite, fluorapatite, wadeite, burbankite, rasvumite, djerfisherite, molybdenite and an incompletely characterized Na-Ca silicate. Alexkhomyakovite occurs as equant grains up to 0.2 mm, veinlets up to 3 cm long and up to 1 mm thick and fine-grained aggregates replacing delhayelite. Alexkhomyakovite is transparent to translucent, colourless, white or grey, with vitreous to greasy lustre. It is brittle, the Mohs hardness is ca. 3. No cleavage was observed, the fracture is uneven. D-meas = 2.25(1), D-calc = 2.196 g cm(-3). Alexkhomyakovite is optically uniaxial (-), omega = 1.543(2), epsilon = 1.476(2). The infrared spectrum is reported. The chemical composition [wt%, electron microprobe data, CO2 and H2O contents calculated for 5 (CO3) and 6 (H2O) per formula unit (pfu), respectively] is: Na2O 4.09, K2O 35.72, CaO 14.92, MnO 0.01, FeO 0.02, SO3 0.11, Cl 4.32, CO2 28.28, H2O 13.90, -O=Cl -0.98, total 100.39. The empirical formula calculated on the basis of 9 metal cations pfu is K5.90Ca2.07Na1.03(CO3)(5)(SO4)(0.01)O0.05Cl0.95 center dot 6H(2)O. The numbers of CO3 groups and H2O molecules are based on structure data. Alexkhomyakovite is hexagonal, P6(3)/mcm, a 9.2691(2), c 15.8419(4) angstrom, V 1178.72(5) angstrom(3) and Z = 2. The strongest reflections of the powder X-ray diffraction pattern [d angstrom(I)(hkl)] are: 7.96(27)(002), 3.486(35)(113), 3.011(100)(114), 2.977(32)(211), 2.676(36)(300), 2.626(42)(213, 115), 2.206(26)(311) and 1.982(17)(008). The crystal structure (solved from single-crystal X-ray diffraction data, R = 0.0578) is unique. It is based on (001) heteropolyhedral layers of pentagonal bipyramids (Ca,Na)O-5(H2O)(2) interconnected via carbonate groups of two types, edge-sharing ones and vertex-sharing ones. Ca and Na are disordered. Ten-fold coordinated K cations centre KO6Cl(H2O)(3) polyhedra on either side of the heteropolyhedral layer. A third type of carbonate group and Cl occupy the interlayer. The mineral is named in honour of the outstanding Russian mineralogist Alexander Petrovich Khomyakov (1933-2012).

KW - Alexkhomyakovite

KW - Crystal structure

KW - Khibiny alkaline complex

KW - Koashva apatite deposit

KW - Kola peninsula

KW - New mineral

KW - Peralkaline pegmatite

KW - Potassium carbonate hydrate

UR - http://www.scopus.com/inward/record.url?scp=85063636435&partnerID=8YFLogxK

U2 - 10.1127/ejm/2018/0030-2798

DO - 10.1127/ejm/2018/0030-2798

M3 - Article

AN - SCOPUS:85063636435

VL - 31

SP - 135

EP - 143

JO - European Journal of Mineralogy

JF - European Journal of Mineralogy

SN - 0935-1221

IS - 1

ER -