Acids with chiral molecules as essential organic compounds of biogenic–abiogenic systems

Elena N. Kotelnikova, Anton I. Isakov, Lyudmila Yu. Kryuchkova, Andrey A. Zolotarev, Sergey N. Bocharov, Heike Lorenz

Результат исследований: Публикации в книгах, отчётах, сборниках, трудах конференцийглава/разделнаучнаярецензирование

Выдержка

The present review generalizes results of a comprehensive experimental study (by means of PXRD, SCXRD, TRPXRD, DSC, IR) of six chiral systems. These are enantiomeric systems of a single substance: (1) the system with a eutectic point (S- and R-E3ClMA), (2) the system forming a binary compound (l- and d-phenylglycine), and (3) the system forming equimolar and non-equimolar discrete compounds (S- and R-malic acid). Also these are diastereomeric systems and a system composed of enantiomers of different substances: (4) the diastereomeric system with continuous solid solutions (l- and l-allo-threonine), and (5) the diastereomeric system with a eutectic point (d- and l-allo-threonine), and (6) the system of enantiomers of different substances (l-valine and l-isoleucine) which contains a non-equimolar discrete compound. Crystal structures of discrete equimolar and non-equimolar homomolecular and heteromolecular compounds found in the systems under discussion are described. Also, polymorph diversity and the limits of solid solutions in such binary systems are discussed.

Язык оригиналаанглийский
Название основной публикацииProcesses and Phenomena on the Boundary Between Biogenic and Abiogenic Nature
Подзаголовок основной публикацииConference proceedings
РедакторыOlga V. Frank-Kamenetskaya, Dmitry Yu. Vlasov, Elena G. Panova, Sofia N. Lessovaia
Место публикацииCham
ИздательSpringer
Страницы695-719
ISBN (электронное издание)9783030216146
ISBN (печатное издание)9783030216139
DOI
СостояниеЭлектронная публикация перед печатью - 30 авг 2019
СобытиеVI International Symposium "Biogenic-abiogenic interactions in natural and anthropogenic systems" devoted to the 150th anniversary of the Saint Petersburg Naturalists Society - СПбГУ, Санкт-Петербург, Российская Федерация
Продолжительность: 24 сен 201827 сен 2018
Номер конференции: VI

Серия публикаций

НазваниеLecture Notes in Earth System Sciences
ISSN (печатное издание)2193-8571
ISSN (электронное издание)2193-858X

Конференция

КонференцияVI International Symposium "Biogenic-abiogenic interactions in natural and anthropogenic systems" devoted to the 150th anniversary of the Saint Petersburg Naturalists Society
СтранаРоссийская Федерация
ГородСанкт-Петербург
Период24/09/1827/09/18

Отпечаток

Enantiomers
solid solution
Organic compounds
Eutectics
Solid solutions
organic compound
Molecules
Acids
acid
Polymorphism
crystal structure
experimental study
Crystal structure
land

Предметные области Scopus

  • Компьютерные технологии в науках о земле
  • Планетоведение и науки о земле (все)

Цитировать

Kotelnikova, E. N., Isakov, A. I., Kryuchkova, L. Y., Zolotarev, A. A., Bocharov, S. N., & Lorenz, H. (2020). Acids with chiral molecules as essential organic compounds of biogenic–abiogenic systems. В O. V. Frank-Kamenetskaya, D. Y. Vlasov, E. G. Panova, & S. N. Lessovaia (Ред.), Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature: Conference proceedings (стр. 695-719). (Lecture Notes in Earth System Sciences). Cham: Springer. https://doi.org/10.1007/978-3-030-21614-6_37
Kotelnikova, Elena N. ; Isakov, Anton I. ; Kryuchkova, Lyudmila Yu. ; Zolotarev, Andrey A. ; Bocharov, Sergey N. ; Lorenz, Heike. / Acids with chiral molecules as essential organic compounds of biogenic–abiogenic systems. Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature: Conference proceedings. редактор / Olga V. Frank-Kamenetskaya ; Dmitry Yu. Vlasov ; Elena G. Panova ; Sofia N. Lessovaia. Cham : Springer, 2020. стр. 695-719 (Lecture Notes in Earth System Sciences).
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author = "Kotelnikova, {Elena N.} and Isakov, {Anton I.} and Kryuchkova, {Lyudmila Yu.} and Zolotarev, {Andrey A.} and Bocharov, {Sergey N.} and Heike Lorenz",
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Kotelnikova, EN, Isakov, AI, Kryuchkova, LY, Zolotarev, AA, Bocharov, SN & Lorenz, H 2020, Acids with chiral molecules as essential organic compounds of biogenic–abiogenic systems. в OV Frank-Kamenetskaya, DY Vlasov, EG Panova & SN Lessovaia (ред.), Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature: Conference proceedings. Lecture Notes in Earth System Sciences, Springer, Cham, стр. 695-719, VI International Symposium "Biogenic-abiogenic interactions in natural and anthropogenic systems" devoted to the 150th anniversary of the Saint Petersburg Naturalists Society, Санкт-Петербург, Российская Федерация, 24/09/18. https://doi.org/10.1007/978-3-030-21614-6_37

Acids with chiral molecules as essential organic compounds of biogenic–abiogenic systems. / Kotelnikova, Elena N.; Isakov, Anton I.; Kryuchkova, Lyudmila Yu.; Zolotarev, Andrey A.; Bocharov, Sergey N.; Lorenz, Heike.

Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature: Conference proceedings. ред. / Olga V. Frank-Kamenetskaya; Dmitry Yu. Vlasov; Elena G. Panova; Sofia N. Lessovaia. Cham : Springer, 2020. стр. 695-719 (Lecture Notes in Earth System Sciences).

Результат исследований: Публикации в книгах, отчётах, сборниках, трудах конференцийглава/разделнаучнаярецензирование

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T1 - Acids with chiral molecules as essential organic compounds of biogenic–abiogenic systems

AU - Kotelnikova, Elena N.

AU - Isakov, Anton I.

AU - Kryuchkova, Lyudmila Yu.

AU - Zolotarev, Andrey A.

AU - Bocharov, Sergey N.

AU - Lorenz, Heike

PY - 2019/8/30

Y1 - 2019/8/30

N2 - The present review generalizes results of a comprehensive experimental study (by means of PXRD, SCXRD, TRPXRD, DSC, IR) of six chiral systems. These are enantiomeric systems of a single substance: (1) the system with a eutectic point (S- and R-E3ClMA), (2) the system forming a binary compound (l- and d-phenylglycine), and (3) the system forming equimolar and non-equimolar discrete compounds (S- and R-malic acid). Also these are diastereomeric systems and a system composed of enantiomers of different substances: (4) the diastereomeric system with continuous solid solutions (l- and l-allo-threonine), and (5) the diastereomeric system with a eutectic point (d- and l-allo-threonine), and (6) the system of enantiomers of different substances (l-valine and l-isoleucine) which contains a non-equimolar discrete compound. Crystal structures of discrete equimolar and non-equimolar homomolecular and heteromolecular compounds found in the systems under discussion are described. Also, polymorph diversity and the limits of solid solutions in such binary systems are discussed.

AB - The present review generalizes results of a comprehensive experimental study (by means of PXRD, SCXRD, TRPXRD, DSC, IR) of six chiral systems. These are enantiomeric systems of a single substance: (1) the system with a eutectic point (S- and R-E3ClMA), (2) the system forming a binary compound (l- and d-phenylglycine), and (3) the system forming equimolar and non-equimolar discrete compounds (S- and R-malic acid). Also these are diastereomeric systems and a system composed of enantiomers of different substances: (4) the diastereomeric system with continuous solid solutions (l- and l-allo-threonine), and (5) the diastereomeric system with a eutectic point (d- and l-allo-threonine), and (6) the system of enantiomers of different substances (l-valine and l-isoleucine) which contains a non-equimolar discrete compound. Crystal structures of discrete equimolar and non-equimolar homomolecular and heteromolecular compounds found in the systems under discussion are described. Also, polymorph diversity and the limits of solid solutions in such binary systems are discussed.

KW - Chiral molecules

KW - Non-equimolar compounds

KW - Organic acids

KW - Phase diagrams

KW - Racemates

KW - Solid solutions

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Kotelnikova EN, Isakov AI, Kryuchkova LY, Zolotarev AA, Bocharov SN, Lorenz H. Acids with chiral molecules as essential organic compounds of biogenic–abiogenic systems. В Frank-Kamenetskaya OV, Vlasov DY, Panova EG, Lessovaia SN, редакторы, Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature: Conference proceedings. Cham: Springer. 2020. стр. 695-719. (Lecture Notes in Earth System Sciences). https://doi.org/10.1007/978-3-030-21614-6_37