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Water in Termally Treated Bioapatites and Their Synthetic Analogues : H-1 NMR Data. / Kalinichenko, Olena A.; Brik, Aleksandr B.; Frank-Kamenetskaya, Olga V.; Kalinichenko, Anatoliy M.; Dudchenko, Natalya O.; Nikolaev, Anton M.

Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature: Conference proceedings. ed. / Olga V. Frank-Kamenetskaya; Dmitry Yu. Vlasov; Elena G. Panova; Sofia N. Lessovaia. Cham : Springer Nature, 2020. p. 79-105 (Lecture Notes in Earth System Sciences).

Research output: Chapter in Book/Report/Conference proceeding › Chapter › Research › peer-review

Harvard

Kalinichenko, OA, Brik, AB, Frank-Kamenetskaya, OV, Kalinichenko, AM, Dudchenko, NO & Nikolaev, AM 2020, Water in Termally Treated Bioapatites and Their Synthetic Analogues: H-1 NMR Data. in OV Frank-Kamenetskaya, DY Vlasov, EG Panova & SN Lessovaia (eds), Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature: Conference proceedings. Lecture Notes in Earth System Sciences, Springer Nature, Cham, pp. 79-105, VI International Symposium "Biogenic-abiogenic interactions in natural and anthropogenic systems", devoted to the 150th anniversary of the Saint-Petersburg Naturalists Society, Saint-Petersburg, Russian Federation, 24/09/18. https://doi.org/10.1007/978-3-030-21614-6_5

APA

Kalinichenko, O. A., Brik, A. B., Frank-Kamenetskaya, O. V., Kalinichenko, A. M., Dudchenko, N. O., & Nikolaev, A. M. (2020). Water in Termally Treated Bioapatites and Their Synthetic Analogues: H-1 NMR Data. In O. V. Frank-Kamenetskaya, D. Y. Vlasov, E. G. Panova, & S. N. Lessovaia (Eds.), Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature: Conference proceedings (pp. 79-105). (Lecture Notes in Earth System Sciences). Springer Nature. https://doi.org/10.1007/978-3-030-21614-6_5

Vancouver

Kalinichenko OA, Brik AB, Frank-Kamenetskaya OV, Kalinichenko AM, Dudchenko NO, Nikolaev AM. Water in Termally Treated Bioapatites and Their Synthetic Analogues: H-1 NMR Data. In Frank-Kamenetskaya OV, Vlasov DY, Panova EG, Lessovaia SN, editors, Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature: Conference proceedings. Cham: Springer Nature. 2020. p. 79-105. (Lecture Notes in Earth System Sciences). https://doi.org/10.1007/978-3-030-21614-6_5

Author

Kalinichenko, Olena A. ; Brik, Aleksandr B. ; Frank-Kamenetskaya, Olga V. ; Kalinichenko, Anatoliy M. ; Dudchenko, Natalya O. ; Nikolaev, Anton M. / Water in Termally Treated Bioapatites and Their Synthetic Analogues : H-1 NMR Data. Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature: Conference proceedings. editor / Olga V. Frank-Kamenetskaya ; Dmitry Yu. Vlasov ; Elena G. Panova ; Sofia N. Lessovaia. Cham : Springer Nature, 2020. pp. 79-105 (Lecture Notes in Earth System Sciences).

BibTeX

@inbook{0d17316fe47f4ec58616c7057ef1711f,
title = "Water in Termally Treated Bioapatites and Their Synthetic Analogues: H-1 NMR Data",
abstract = "The molecular water incorporation in bioapatites obtained by bone pyrolysis at temperatures of 600–1100 °C has been investigated using in situ solid 1H nuclear magnetic resonance (solid 1H NMR) method in the temperature range of T = 25–300 °C and, in addition, 1H magic-angle spinning NMR, X-ray diffraction and infrared spectroscopy at room temperature. For comparison, synthetic analogues of bioapatite, precipitated hydroxyapatite (HA), HA with La impurity and carbonate fluorapatite were investigated as well. It was established that there are water molecules adsorbed on crystallites surfaces and bound in structure (H2Os) in studied apatites. More rigid H2Os1 molecules cause the doublet under normal conditions and the wide singlet at T ≥ 150 °C in situ 1H solid NMR spectra. In addition, H2Os3 molecules with reorientation mobility at T = 150–300 °C are presented in bioapatite and HA annealed at lower temperatures and La-HA. Water incorporation into structure of bioapatite annealed at 600–1100 °C and its synthetic analogues HA is established to be zeolite-like. Presumably, the configuration of cavities is formed in the apatite crystal scaffold during annealing of studied apatites. These cavities are related with vacancy clusters in original structures and connected between themselves and with surface by the channels with a diameter of not more than 0.3 nm. Water molecules trapped in smaller (H2Os2) and larger cavities (H2Os1) cause the doublet and singlet, respectively; water molecules in OH vacancies in channels (H2Os3) are due to narrow lines.",
keywords = "Bioapatite, Biomimetic apatites, Solid-state H NMR, Structural water, Thermal treatment",
author = "Kalinichenko, {Olena A.} and Brik, {Aleksandr B.} and Frank-Kamenetskaya, {Olga V.} and Kalinichenko, {Anatoliy M.} and Dudchenko, {Natalya O.} and Nikolaev, {Anton M.}",
note = "Publisher Copyright: {\textcopyright} Springer Nature Switzerland AG 2020. Copyright: Copyright 2020 Elsevier B.V., All rights reserved.; null ; Conference date: 24-09-2018 Through 27-09-2018",
year = "2020",
doi = "10.1007/978-3-030-21614-6_5",
language = "English",
isbn = "9783030216139",
series = "Lecture Notes in Earth System Sciences",
publisher = "Springer Nature",
pages = "79--105",
editor = "Frank-Kamenetskaya, {Olga V. } and Vlasov, {Dmitry Yu. } and Panova, {Elena G. } and Lessovaia, {Sofia N. }",
booktitle = "Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature",
address = "Germany",

}

RIS

TY - CHAP

T1 - Water in Termally Treated Bioapatites and Their Synthetic Analogues

AU - Kalinichenko, Olena A.

AU - Brik, Aleksandr B.

AU - Frank-Kamenetskaya, Olga V.

AU - Kalinichenko, Anatoliy M.

AU - Dudchenko, Natalya O.

AU - Nikolaev, Anton M.

N1 - Conference code: VI

PY - 2020

Y1 - 2020

N2 - The molecular water incorporation in bioapatites obtained by bone pyrolysis at temperatures of 600–1100 °C has been investigated using in situ solid 1H nuclear magnetic resonance (solid 1H NMR) method in the temperature range of T = 25–300 °C and, in addition, 1H magic-angle spinning NMR, X-ray diffraction and infrared spectroscopy at room temperature. For comparison, synthetic analogues of bioapatite, precipitated hydroxyapatite (HA), HA with La impurity and carbonate fluorapatite were investigated as well. It was established that there are water molecules adsorbed on crystallites surfaces and bound in structure (H2Os) in studied apatites. More rigid H2Os1 molecules cause the doublet under normal conditions and the wide singlet at T ≥ 150 °C in situ 1H solid NMR spectra. In addition, H2Os3 molecules with reorientation mobility at T = 150–300 °C are presented in bioapatite and HA annealed at lower temperatures and La-HA. Water incorporation into structure of bioapatite annealed at 600–1100 °C and its synthetic analogues HA is established to be zeolite-like. Presumably, the configuration of cavities is formed in the apatite crystal scaffold during annealing of studied apatites. These cavities are related with vacancy clusters in original structures and connected between themselves and with surface by the channels with a diameter of not more than 0.3 nm. Water molecules trapped in smaller (H2Os2) and larger cavities (H2Os1) cause the doublet and singlet, respectively; water molecules in OH vacancies in channels (H2Os3) are due to narrow lines.

AB - The molecular water incorporation in bioapatites obtained by bone pyrolysis at temperatures of 600–1100 °C has been investigated using in situ solid 1H nuclear magnetic resonance (solid 1H NMR) method in the temperature range of T = 25–300 °C and, in addition, 1H magic-angle spinning NMR, X-ray diffraction and infrared spectroscopy at room temperature. For comparison, synthetic analogues of bioapatite, precipitated hydroxyapatite (HA), HA with La impurity and carbonate fluorapatite were investigated as well. It was established that there are water molecules adsorbed on crystallites surfaces and bound in structure (H2Os) in studied apatites. More rigid H2Os1 molecules cause the doublet under normal conditions and the wide singlet at T ≥ 150 °C in situ 1H solid NMR spectra. In addition, H2Os3 molecules with reorientation mobility at T = 150–300 °C are presented in bioapatite and HA annealed at lower temperatures and La-HA. Water incorporation into structure of bioapatite annealed at 600–1100 °C and its synthetic analogues HA is established to be zeolite-like. Presumably, the configuration of cavities is formed in the apatite crystal scaffold during annealing of studied apatites. These cavities are related with vacancy clusters in original structures and connected between themselves and with surface by the channels with a diameter of not more than 0.3 nm. Water molecules trapped in smaller (H2Os2) and larger cavities (H2Os1) cause the doublet and singlet, respectively; water molecules in OH vacancies in channels (H2Os3) are due to narrow lines.

KW - Bioapatite

KW - Biomimetic apatites

KW - Solid-state H NMR

KW - Structural water

KW - Thermal treatment

UR - http://www.scopus.com/inward/record.url?scp=85072087465&partnerID=8YFLogxK

U2 - 10.1007/978-3-030-21614-6_5

DO - 10.1007/978-3-030-21614-6_5

M3 - Chapter

AN - SCOPUS:85072087465

SN - 9783030216139

T3 - Lecture Notes in Earth System Sciences

SP - 79

EP - 105

BT - Processes and Phenomena on the Boundary Between Biogenic and Abiogenic Nature

A2 - Frank-Kamenetskaya, Olga V.

A2 - Vlasov, Dmitry Yu.

A2 - Panova, Elena G.

A2 - Lessovaia, Sofia N.

PB - Springer Nature

CY - Cham

Y2 - 24 September 2018 through 27 September 2018

ER -

ID: 46330833