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Ultrasound-assisted synthesis of luminescent micro-and nanocrystalline eu-based mofs as luminescent probes for heavy metal ions. / Kolesnik, Stefaniia S.; Nosov, Viktor G.; Kolesnikov, Ilya E.; Khairullina, Evgenia M.; Tumkin, Ilya I.; Vidyakina, Aleksandra A.; Sysoeva, Alevtina A.; Ryazantsev, Mikhail N.; Panov, Maxim S.; Khripun, Vasiliy D.; Bogachev, Nikita A.; Skripkin, Mikhail Yu; Mereshchenko, Andrey S.

In: Nanomaterials, Vol. 11, No. 9, 2448, 20.09.2021.

Research output: Contribution to journal › Article › peer-review

Harvard

Kolesnik, SS, Nosov, VG, Kolesnikov, IE, Khairullina, EM, Tumkin, II, Vidyakina, AA, Sysoeva, AA, Ryazantsev, MN, Panov, MS, Khripun, VD, Bogachev, NA, Skripkin, MY & Mereshchenko, AS 2021, 'Ultrasound-assisted synthesis of luminescent micro-and nanocrystalline eu-based mofs as luminescent probes for heavy metal ions', Nanomaterials, vol. 11, no. 9, 2448. https://doi.org/10.3390/nano11092448, https://doi.org/10.3390/nano11092448

APA

Kolesnik, S. S., Nosov, V. G., Kolesnikov, I. E., Khairullina, E. M., Tumkin, I. I., Vidyakina, A. A., Sysoeva, A. A., Ryazantsev, M. N., Panov, M. S., Khripun, V. D., Bogachev, N. A., Skripkin, M. Y., & Mereshchenko, A. S. (2021). Ultrasound-assisted synthesis of luminescent micro-and nanocrystalline eu-based mofs as luminescent probes for heavy metal ions. Nanomaterials, 11(9), [2448]. https://doi.org/10.3390/nano11092448, https://doi.org/10.3390/nano11092448

Vancouver

Kolesnik SS, Nosov VG, Kolesnikov IE, Khairullina EM, Tumkin II, Vidyakina AA et al. Ultrasound-assisted synthesis of luminescent micro-and nanocrystalline eu-based mofs as luminescent probes for heavy metal ions. Nanomaterials. 2021 Sep 20;11(9). 2448. https://doi.org/10.3390/nano11092448, https://doi.org/10.3390/nano11092448

Author

Kolesnik, Stefaniia S. ; Nosov, Viktor G. ; Kolesnikov, Ilya E. ; Khairullina, Evgenia M. ; Tumkin, Ilya I. ; Vidyakina, Aleksandra A. ; Sysoeva, Alevtina A. ; Ryazantsev, Mikhail N. ; Panov, Maxim S. ; Khripun, Vasiliy D. ; Bogachev, Nikita A. ; Skripkin, Mikhail Yu ; Mereshchenko, Andrey S. / Ultrasound-assisted synthesis of luminescent micro-and nanocrystalline eu-based mofs as luminescent probes for heavy metal ions. In: Nanomaterials. 2021 ; Vol. 11, No. 9.

BibTeX

@article{8f1b18ef975c43fe8413fbca6f3562fd,
title = "Ultrasound-assisted synthesis of luminescent micro-and nanocrystalline eu-based mofs as luminescent probes for heavy metal ions",
abstract = "The luminescent coarse-, micro-and nanocrystalline europium(III) terephthalate tetrahy-drate (Eu2bdc3‧4H2O) metal-organic frameworks were synthesized by the ultrasound-assisted wet-chemical method. Electron micrographs show that the europium(III) terephthalate microparticles are 7 μm long leaf-like plates. According to the dynamic light scattering technique, the average size of the Eu2bdc3‧4H2O nanoparticles is equal to about 8 ± 2 nm. Thereby, the reported Eu2bdc3‧4H2O nanoparticles are the smallest nanosized rare-earth-based MOF crystals, to the best of our knowledge. The synthesized materials demonstrate red emission due to the5D0–7FJ transitions of Eu3+ upon 250 nm excitation into1ππ* state of the terephthalate ion. Size reduction results in broad-ened emission bands, an increase in the non-radiative rate constants and a decrease in both the quantum efficiency of the5D0 level and Eu3+ and the luminescence quantum yields. Cu2+, Cr3+, and Fe3+ ions efficiently and selectively quench the luminescence of nanocrystalline europium(III) ter-ephthalate, which makes it a prospective material for luminescent probes to monitor these ions in waste and drinking water.",
keywords = "Europium, Luminescence, Luminescent probe, Metal-organic framework, Nanoparticle, Rare earth, FE(III), luminescent probe, PROTON CONDUCTIVITY, SORPTION, nanoparticle, SENSOR, metal-organic framework, luminescence, europium, FE3+, rare earth, ORGANIC FRAMEWORK, FLUORESCENT-PROBE, BASIC PYRIDYL SITES",
author = "Kolesnik, {Stefaniia S.} and Nosov, {Viktor G.} and Kolesnikov, {Ilya E.} and Khairullina, {Evgenia M.} and Tumkin, {Ilya I.} and Vidyakina, {Aleksandra A.} and Sysoeva, {Alevtina A.} and Ryazantsev, {Mikhail N.} and Panov, {Maxim S.} and Khripun, {Vasiliy D.} and Bogachev, {Nikita A.} and Skripkin, {Mikhail Yu} and Mereshchenko, {Andrey S.}",
note = "Publisher Copyright: {\textcopyright} 2021 by the authors. Licensee MDPI, Basel, Switzerland.",
year = "2021",
month = sep,
day = "20",
doi = "10.3390/nano11092448",
language = "English",
volume = "11",
journal = "Nanomaterials",
issn = "2079-4991",
publisher = "MDPI AG",
number = "9",

}

RIS

TY - JOUR

T1 - Ultrasound-assisted synthesis of luminescent micro-and nanocrystalline eu-based mofs as luminescent probes for heavy metal ions

AU - Kolesnik, Stefaniia S.

AU - Nosov, Viktor G.

AU - Kolesnikov, Ilya E.

AU - Khairullina, Evgenia M.

AU - Tumkin, Ilya I.

AU - Vidyakina, Aleksandra A.

AU - Sysoeva, Alevtina A.

AU - Ryazantsev, Mikhail N.

AU - Panov, Maxim S.

AU - Khripun, Vasiliy D.

AU - Bogachev, Nikita A.

AU - Skripkin, Mikhail Yu

AU - Mereshchenko, Andrey S.

N1 - Publisher Copyright: © 2021 by the authors. Licensee MDPI, Basel, Switzerland.

PY - 2021/9/20

Y1 - 2021/9/20

N2 - The luminescent coarse-, micro-and nanocrystalline europium(III) terephthalate tetrahy-drate (Eu2bdc3‧4H2O) metal-organic frameworks were synthesized by the ultrasound-assisted wet-chemical method. Electron micrographs show that the europium(III) terephthalate microparticles are 7 μm long leaf-like plates. According to the dynamic light scattering technique, the average size of the Eu2bdc3‧4H2O nanoparticles is equal to about 8 ± 2 nm. Thereby, the reported Eu2bdc3‧4H2O nanoparticles are the smallest nanosized rare-earth-based MOF crystals, to the best of our knowledge. The synthesized materials demonstrate red emission due to the5D0–7FJ transitions of Eu3+ upon 250 nm excitation into1ππ* state of the terephthalate ion. Size reduction results in broad-ened emission bands, an increase in the non-radiative rate constants and a decrease in both the quantum efficiency of the5D0 level and Eu3+ and the luminescence quantum yields. Cu2+, Cr3+, and Fe3+ ions efficiently and selectively quench the luminescence of nanocrystalline europium(III) ter-ephthalate, which makes it a prospective material for luminescent probes to monitor these ions in waste and drinking water.

AB - The luminescent coarse-, micro-and nanocrystalline europium(III) terephthalate tetrahy-drate (Eu2bdc3‧4H2O) metal-organic frameworks were synthesized by the ultrasound-assisted wet-chemical method. Electron micrographs show that the europium(III) terephthalate microparticles are 7 μm long leaf-like plates. According to the dynamic light scattering technique, the average size of the Eu2bdc3‧4H2O nanoparticles is equal to about 8 ± 2 nm. Thereby, the reported Eu2bdc3‧4H2O nanoparticles are the smallest nanosized rare-earth-based MOF crystals, to the best of our knowledge. The synthesized materials demonstrate red emission due to the5D0–7FJ transitions of Eu3+ upon 250 nm excitation into1ππ* state of the terephthalate ion. Size reduction results in broad-ened emission bands, an increase in the non-radiative rate constants and a decrease in both the quantum efficiency of the5D0 level and Eu3+ and the luminescence quantum yields. Cu2+, Cr3+, and Fe3+ ions efficiently and selectively quench the luminescence of nanocrystalline europium(III) ter-ephthalate, which makes it a prospective material for luminescent probes to monitor these ions in waste and drinking water.

KW - Europium

KW - Luminescence

KW - Luminescent probe

KW - Metal-organic framework

KW - Nanoparticle

KW - Rare earth

KW - FE(III)

KW - luminescent probe

KW - PROTON CONDUCTIVITY

KW - SORPTION

KW - nanoparticle

KW - SENSOR

KW - metal-organic framework

KW - luminescence

KW - europium

KW - FE3+

KW - rare earth

KW - ORGANIC FRAMEWORK

KW - FLUORESCENT-PROBE

KW - BASIC PYRIDYL SITES

UR - http://www.scopus.com/inward/record.url?scp=85115155423&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/ded51a6e-e242-3fcf-80f9-cb3c55ac6370/

U2 - 10.3390/nano11092448

DO - 10.3390/nano11092448

M3 - Article

AN - SCOPUS:85115155423

VL - 11

JO - Nanomaterials

JF - Nanomaterials

SN - 2079-4991

IS - 9

M1 - 2448

ER -

ID: 86366136