Thermal behavior of borate BaBiBO4

S.N. Volkov, R.S. Bubnova, V.G. Zalesskii, A.V. Egorysheva, V.D. Volodin, S.K. Filatov

Research output

2 Citations (Scopus)

Abstract

© 2015, Pleiades Publishing, Ltd.The thermal behavior of barium and bismuth borate BaBiBO4 is studied by X-ray powder and single-crystal diffraction in a wide temperature range, as well as by the methods of differential scanning calorimetry and dielectric spectroscopy. Thermal expansion is anisotropic, which is caused by the orientation of BO3 boron-oxygen groups. With increasing temperature, the degree of anisotropy of thermal expansion increases up to negative. In the temperature range of 700–800 K, an anomaly of the dielectric properties is observed, accompanied by the change of the temperature dependence of the coefficients of thermal expansion and the heat capacity.
Original languageEnglish
Pages (from-to)622-629
JournalGlass Physics and Chemistry
Issue number6
DOIs
Publication statusPublished - 2015

Fingerprint

Borates
borates
thermal expansion
Thermal expansion
Dielectric spectroscopy
Temperature
bismuth
Bismuth
Boron
barium
temperature
dielectric properties
boron
Barium
heat measurement
specific heat
Dielectric properties
Powders
anomalies
Specific heat

Cite this

Volkov, S. N., Bubnova, R. S., Zalesskii, V. G., Egorysheva, A. V., Volodin, V. D., & Filatov, S. K. (2015). Thermal behavior of borate BaBiBO4. Glass Physics and Chemistry, (6), 622-629. https://doi.org/10.1134/S108765961506019X
Volkov, S.N. ; Bubnova, R.S. ; Zalesskii, V.G. ; Egorysheva, A.V. ; Volodin, V.D. ; Filatov, S.K. / Thermal behavior of borate BaBiBO4. In: Glass Physics and Chemistry. 2015 ; No. 6. pp. 622-629.
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Volkov, SN, Bubnova, RS, Zalesskii, VG, Egorysheva, AV, Volodin, VD & Filatov, SK 2015, 'Thermal behavior of borate BaBiBO4', Glass Physics and Chemistry, no. 6, pp. 622-629. https://doi.org/10.1134/S108765961506019X

Thermal behavior of borate BaBiBO4. / Volkov, S.N.; Bubnova, R.S.; Zalesskii, V.G.; Egorysheva, A.V.; Volodin, V.D.; Filatov, S.K.

In: Glass Physics and Chemistry, No. 6, 2015, p. 622-629.

Research output

TY - JOUR

T1 - Thermal behavior of borate BaBiBO4

AU - Volkov, S.N.

AU - Bubnova, R.S.

AU - Zalesskii, V.G.

AU - Egorysheva, A.V.

AU - Volodin, V.D.

AU - Filatov, S.K.

PY - 2015

Y1 - 2015

N2 - © 2015, Pleiades Publishing, Ltd.The thermal behavior of barium and bismuth borate BaBiBO4 is studied by X-ray powder and single-crystal diffraction in a wide temperature range, as well as by the methods of differential scanning calorimetry and dielectric spectroscopy. Thermal expansion is anisotropic, which is caused by the orientation of BO3 boron-oxygen groups. With increasing temperature, the degree of anisotropy of thermal expansion increases up to negative. In the temperature range of 700–800 K, an anomaly of the dielectric properties is observed, accompanied by the change of the temperature dependence of the coefficients of thermal expansion and the heat capacity.

AB - © 2015, Pleiades Publishing, Ltd.The thermal behavior of barium and bismuth borate BaBiBO4 is studied by X-ray powder and single-crystal diffraction in a wide temperature range, as well as by the methods of differential scanning calorimetry and dielectric spectroscopy. Thermal expansion is anisotropic, which is caused by the orientation of BO3 boron-oxygen groups. With increasing temperature, the degree of anisotropy of thermal expansion increases up to negative. In the temperature range of 700–800 K, an anomaly of the dielectric properties is observed, accompanied by the change of the temperature dependence of the coefficients of thermal expansion and the heat capacity.

U2 - 10.1134/S108765961506019X

DO - 10.1134/S108765961506019X

M3 - Article

SP - 622

EP - 629

JO - Glass Physics and Chemistry

JF - Glass Physics and Chemistry

SN - 1087-6596

IS - 6

ER -

Volkov SN, Bubnova RS, Zalesskii VG, Egorysheva AV, Volodin VD, Filatov SK. Thermal behavior of borate BaBiBO4. Glass Physics and Chemistry. 2015;(6):622-629. https://doi.org/10.1134/S108765961506019X