The study of bis-chloromethyl-phosphinic acid crystal by ATR and Raman spectroscopy and X-ray diffraction

Research output

Abstract

Crystals of bis-chloromethyl-phosphinic acid ((CH 2 Cl) 2 POOH) are studied by attenuated total reflection (ATR) and Raman spectroscopy supported by X-Ray diffraction. The bands recorded in the ATR and in Raman spectra have the same wavenumbers within experimental uncertainty. It is in agreement with the X-Ray diffraction results which show that the molecules in crystals form infinite chains through hydrogen bonds and there is no center of inversion. The parameters of the unit cell, the bond lengths and angles, and the distance between two oxygen atoms in hydrogen bond bridges are determined. The spectral features and the intermolecular distance between oxygen atoms are characteristic for a strong hydrogen bonded system.

Original languageEnglish
Pages (from-to)219-227
Number of pages9
JournalMolecular Crystals and Liquid Crystals
Volume665
Issue number1
DOIs
Publication statusPublished - 13 Apr 2018

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Phosphinic Acids
Raman spectroscopy
oxygen atoms
Hydrogen bonds
hydrogen bonds
Oxygen
X ray diffraction
Atoms
Crystals
acids
Acids
Bond length
diffraction
crystals
Raman scattering
Hydrogen
x rays
methylidyne
inversions
Raman spectra

Scopus subject areas

  • Chemistry(all)
  • Materials Science(all)
  • Condensed Matter Physics

Cite this

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title = "The study of bis-chloromethyl-phosphinic acid crystal by ATR and Raman spectroscopy and X-ray diffraction",
abstract = "Crystals of bis-chloromethyl-phosphinic acid ((CH 2 Cl) 2 POOH) are studied by attenuated total reflection (ATR) and Raman spectroscopy supported by X-Ray diffraction. The bands recorded in the ATR and in Raman spectra have the same wavenumbers within experimental uncertainty. It is in agreement with the X-Ray diffraction results which show that the molecules in crystals form infinite chains through hydrogen bonds and there is no center of inversion. The parameters of the unit cell, the bond lengths and angles, and the distance between two oxygen atoms in hydrogen bond bridges are determined. The spectral features and the intermolecular distance between oxygen atoms are characteristic for a strong hydrogen bonded system.",
keywords = "(CH Cl) POOH, ATR spectra, crystal structure, H-bond, Raman spectra, X-Ray diffraction",
author = "Glazachev, {Eugeny V.} and Avdontceva, {Margarita S.} and Asfin, {Ruslan E.}",
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T1 - The study of bis-chloromethyl-phosphinic acid crystal by ATR and Raman spectroscopy and X-ray diffraction

AU - Glazachev, Eugeny V.

AU - Avdontceva, Margarita S.

AU - Asfin, Ruslan E.

PY - 2018/4/13

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N2 - Crystals of bis-chloromethyl-phosphinic acid ((CH 2 Cl) 2 POOH) are studied by attenuated total reflection (ATR) and Raman spectroscopy supported by X-Ray diffraction. The bands recorded in the ATR and in Raman spectra have the same wavenumbers within experimental uncertainty. It is in agreement with the X-Ray diffraction results which show that the molecules in crystals form infinite chains through hydrogen bonds and there is no center of inversion. The parameters of the unit cell, the bond lengths and angles, and the distance between two oxygen atoms in hydrogen bond bridges are determined. The spectral features and the intermolecular distance between oxygen atoms are characteristic for a strong hydrogen bonded system.

AB - Crystals of bis-chloromethyl-phosphinic acid ((CH 2 Cl) 2 POOH) are studied by attenuated total reflection (ATR) and Raman spectroscopy supported by X-Ray diffraction. The bands recorded in the ATR and in Raman spectra have the same wavenumbers within experimental uncertainty. It is in agreement with the X-Ray diffraction results which show that the molecules in crystals form infinite chains through hydrogen bonds and there is no center of inversion. The parameters of the unit cell, the bond lengths and angles, and the distance between two oxygen atoms in hydrogen bond bridges are determined. The spectral features and the intermolecular distance between oxygen atoms are characteristic for a strong hydrogen bonded system.

KW - (CH Cl) POOH

KW - ATR spectra

KW - crystal structure

KW - H-bond

KW - Raman spectra

KW - X-Ray diffraction

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