Standard

The nature of current carriers and electric conductivity in the PbCl2-2PbO · SiO2 glasses. / Sokolov, I. A.; Murin, I. V.; Wiemhöfer, H. D.; Pronkin, A. A.

In: Glass Physics and Chemistry, Vol. 26, No. 1, 2000, p. 148-157.

Research output: Contribution to journal › Article › peer-review

Harvard

Sokolov, IA, Murin, IV, Wiemhöfer, HD & Pronkin, AA 2000, 'The nature of current carriers and electric conductivity in the PbCl2-2PbO · SiO2 glasses', Glass Physics and Chemistry, vol. 26, no. 1, pp. 148-157.

APA

Sokolov, I. A., Murin, I. V., Wiemhöfer, H. D., & Pronkin, A. A. (2000). The nature of current carriers and electric conductivity in the PbCl2-2PbO · SiO2 glasses. Glass Physics and Chemistry, 26(1), 148-157.

Vancouver

Sokolov IA, Murin IV, Wiemhöfer HD, Pronkin AA. The nature of current carriers and electric conductivity in the PbCl2-2PbO · SiO2 glasses. Glass Physics and Chemistry. 2000;26(1):148-157.

Author

Sokolov, I. A. ; Murin, I. V. ; Wiemhöfer, H. D. ; Pronkin, A. A. / The nature of current carriers and electric conductivity in the PbCl2-2PbO · SiO2 glasses. In: Glass Physics and Chemistry. 2000 ; Vol. 26, No. 1. pp. 148-157.

BibTeX

@article{cf64dcb2ab054f97b2a0d324aa0f2092,
title = "The nature of current carriers and electric conductivity in the PbCl2-2PbO · SiO2 glasses",
abstract = "The nature of current carriers is revealed and the concentration dependence of the true transport numbers of chlorine ions η is studied by the Tubandt method in glasses of the PbCl2-2PbO · SiO2 system. It is demonstrated that, in glasses containing up to ∼20 mol % PbCl2, the electricity transport occurs through protons and chlorine ions. At [PbCl2] ≥ 20 mol %, the electric current is carried primarily by the chlorine ions. The known crystalline compounds in the PbO-PbCl2 system are synthesized, and the temperature dependences of their electric conductivity are investigated for the first time. It is found that the introduction of PbCl2 into PbO is accompanied, first, by an increase in the electric conductivity (to a PbCl2 mole fraction of ∼0.5), and, then (when PbCl2 single crystals are formed), by its decrease. The temperature-concentration dependence of the electric conductivity for glasses in the PbCl2-2PbO · SiO2 system is interpreted in terms of structural-chemical microinhomogeneity of the glass structure due to the selective interaction of components during the glass synthesis.",
author = "Sokolov, {I. A.} and Murin, {I. V.} and Wiemh{\"o}fer, {H. D.} and Pronkin, {A. A.}",
year = "2000",
language = "English",
volume = "26",
pages = "148--157",
journal = "Glass Physics and Chemistry",
issn = "1087-6596",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "1",

}

RIS

TY - JOUR

T1 - The nature of current carriers and electric conductivity in the PbCl2-2PbO · SiO2 glasses

AU - Sokolov, I. A.

AU - Murin, I. V.

AU - Wiemhöfer, H. D.

AU - Pronkin, A. A.

PY - 2000

Y1 - 2000

N2 - The nature of current carriers is revealed and the concentration dependence of the true transport numbers of chlorine ions η is studied by the Tubandt method in glasses of the PbCl2-2PbO · SiO2 system. It is demonstrated that, in glasses containing up to ∼20 mol % PbCl2, the electricity transport occurs through protons and chlorine ions. At [PbCl2] ≥ 20 mol %, the electric current is carried primarily by the chlorine ions. The known crystalline compounds in the PbO-PbCl2 system are synthesized, and the temperature dependences of their electric conductivity are investigated for the first time. It is found that the introduction of PbCl2 into PbO is accompanied, first, by an increase in the electric conductivity (to a PbCl2 mole fraction of ∼0.5), and, then (when PbCl2 single crystals are formed), by its decrease. The temperature-concentration dependence of the electric conductivity for glasses in the PbCl2-2PbO · SiO2 system is interpreted in terms of structural-chemical microinhomogeneity of the glass structure due to the selective interaction of components during the glass synthesis.

AB - The nature of current carriers is revealed and the concentration dependence of the true transport numbers of chlorine ions η is studied by the Tubandt method in glasses of the PbCl2-2PbO · SiO2 system. It is demonstrated that, in glasses containing up to ∼20 mol % PbCl2, the electricity transport occurs through protons and chlorine ions. At [PbCl2] ≥ 20 mol %, the electric current is carried primarily by the chlorine ions. The known crystalline compounds in the PbO-PbCl2 system are synthesized, and the temperature dependences of their electric conductivity are investigated for the first time. It is found that the introduction of PbCl2 into PbO is accompanied, first, by an increase in the electric conductivity (to a PbCl2 mole fraction of ∼0.5), and, then (when PbCl2 single crystals are formed), by its decrease. The temperature-concentration dependence of the electric conductivity for glasses in the PbCl2-2PbO · SiO2 system is interpreted in terms of structural-chemical microinhomogeneity of the glass structure due to the selective interaction of components during the glass synthesis.

UR - http://www.scopus.com/inward/record.url?scp=0034341279&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0034341279

VL - 26

SP - 148

EP - 157

JO - Glass Physics and Chemistry

JF - Glass Physics and Chemistry

SN - 1087-6596

IS - 1

ER -

ID: 88011185