Research output: Contribution to journal › Article › peer-review
The impact of dimensionality and stoichiometry of CuBr on its coupling to sp2-carbon. / Eliseev, Andrei A.; Verbitskiy, Nikolay I.; Volykhov, Andrei A.; Fedorov, Alexander V.; Vilkov, Oleg Yu; Verbitskiy, Ivan I.; Brzhezinskaya, Maria M.; Kiselev, Nikolay A.; Yashina, Lada V.
In: Carbon, Vol. 99, 2016, p. 619-623.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - The impact of dimensionality and stoichiometry of CuBr on its coupling to sp2-carbon
AU - Eliseev, Andrei A.
AU - Verbitskiy, Nikolay I.
AU - Volykhov, Andrei A.
AU - Fedorov, Alexander V.
AU - Vilkov, Oleg Yu
AU - Verbitskiy, Ivan I.
AU - Brzhezinskaya, Maria M.
AU - Kiselev, Nikolay A.
AU - Yashina, Lada V.
PY - 2016
Y1 - 2016
N2 - A possible coupling of one-dimensional crystal to their template material plays crucial role when its electronic structure is evaluated. Here a comparative study of the interaction between CuBr and sp2-carbon in 1D and 2D structures as probed by X-ray absorption, photoemission and DFT calculations is reported. The 1D system, i.e. a non-stoichiometric CuBr crystal embedded into a single-walled carbon nanotube (CuBr@SWNT) revealed notable hybridization in contrast to a CuBr film deposited on graphene or graphite. CuBr is coupled to the nanotube due to its low dimensionality and strong coordination deficiency of atoms thus forming one-dimensional nanocrystal, which is non-free-standing.
AB - A possible coupling of one-dimensional crystal to their template material plays crucial role when its electronic structure is evaluated. Here a comparative study of the interaction between CuBr and sp2-carbon in 1D and 2D structures as probed by X-ray absorption, photoemission and DFT calculations is reported. The 1D system, i.e. a non-stoichiometric CuBr crystal embedded into a single-walled carbon nanotube (CuBr@SWNT) revealed notable hybridization in contrast to a CuBr film deposited on graphene or graphite. CuBr is coupled to the nanotube due to its low dimensionality and strong coordination deficiency of atoms thus forming one-dimensional nanocrystal, which is non-free-standing.
UR - http://www.scopus.com/inward/record.url?scp=84959387242&partnerID=8YFLogxK
U2 - 10.1016/j.carbon.2015.12.031
DO - 10.1016/j.carbon.2015.12.031
M3 - Article
AN - SCOPUS:84959387242
VL - 99
SP - 619
EP - 623
JO - Carbon
JF - Carbon
SN - 0008-6223
ER -
ID: 9289900