Research output: Contribution to journal › Article › peer-review
Synthesis of polystyrene by the ATRP process with a catalyst based on a novel copper (II) thiadiazol complex: Investigation and application. / Еремин, Алексей; Гостев, Алексей; Непочатый, Георгий; Сивцов, Евгений; Горбунов, Павел; Пузырьков, Артур Александрович; Егоров, Семен Сергеевич; Матвиенко, Владислав; Красиков, Валерий; Попова, Екатерина; Дмитренко, Мария Евгеньевна; Кузьминова, Анна Игоревна; Пенькова, Анастасия Владимировна; Селютин, Артем Александрович.
In: Nano-Structures and Nano-Objects, Vol. 41, 101445, 01.02.2025.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Synthesis of polystyrene by the ATRP process with a catalyst based on a novel copper (II) thiadiazol complex:
T2 - Investigation and application
AU - Еремин, Алексей
AU - Гостев, Алексей
AU - Непочатый, Георгий
AU - Сивцов, Евгений
AU - Горбунов, Павел
AU - Пузырьков, Артур Александрович
AU - Егоров, Семен Сергеевич
AU - Матвиенко, Владислав
AU - Красиков, Валерий
AU - Попова, Екатерина
AU - Дмитренко, Мария Евгеньевна
AU - Кузьминова, Анна Игоревна
AU - Пенькова, Анастасия Владимировна
AU - Селютин, Артем Александрович
PY - 2025/2/1
Y1 - 2025/2/1
N2 - There are majority ways to design polymeric materials including the synthesis of polymers with molecular weights in a given range and their modification with different nanoparticles to create composites. Due to this, the synthesis of a novel catalyst based on a copper thiadiazol complex for the ATRP polymerization to develop polystyrene (PS) and metal-organic framework (CrMOF, accepted abbreviation MIL-101) based on chromium (III) and trimesic acid by a novel approach was carried out to obtain novel composite material. The developed PS and PS/CrMOF composite were applied as membranes in pervaporation for the hydrazine concentration to evaluate their potential use as membrane materials. The structural and physicochemical properties of synthesized substances and developed composites were studied by various analysis methods.
AB - There are majority ways to design polymeric materials including the synthesis of polymers with molecular weights in a given range and their modification with different nanoparticles to create composites. Due to this, the synthesis of a novel catalyst based on a copper thiadiazol complex for the ATRP polymerization to develop polystyrene (PS) and metal-organic framework (CrMOF, accepted abbreviation MIL-101) based on chromium (III) and trimesic acid by a novel approach was carried out to obtain novel composite material. The developed PS and PS/CrMOF composite were applied as membranes in pervaporation for the hydrazine concentration to evaluate their potential use as membrane materials. The structural and physicochemical properties of synthesized substances and developed composites were studied by various analysis methods.
KW - ATRP
KW - Catalyst
KW - Hydrazine
KW - Membrane
KW - Nanoparticles
KW - Pervaporation
UR - https://www.mendeley.com/catalogue/1ac6eca6-b96a-3946-b091-03e29376ea96/
U2 - 10.1016/j.nanoso.2025.101445
DO - 10.1016/j.nanoso.2025.101445
M3 - Article
VL - 41
JO - Nano-Structures and Nano-Objects
JF - Nano-Structures and Nano-Objects
SN - 2352-507X
M1 - 101445
ER -
ID: 127406543