SYNTHESIS AND CHEMICAL-TRANSFORMATIONS OF ARYL-SUBSTITUTED POLY(BENZYLMETHACRYLATES

A.Yu Bilibin, VV Zabolotnyi, VE Kukkonen, A.F. Shelikh

Research output

Abstract

A series of poly(benzyl methacrylates) was prepared by radical polymerization of substituted benzyl esters of methacrylic acid. The polymers are X-ray amorphous, their M(n) are within the (4.7 - 6.2) 10(3) range, thus corresponding to the degree of polymerization of 23 - 30. Poly(benzyl methacrylates) were characterized using UV, IR, and NMR spectroscopy. The effect of substituents on the possibility of acid-catalyzed transformation of poly(benzyl methacrylates) into poly(methacrylic acid) is estimated.
Original languageUndefined
Pages (from-to)43-46
JournalJournal of polymer science. Part B, Polymer letters
Volume37, сер.В
Issue number1-2
Publication statusPublished - 1995
Externally publishedYes

Cite this

Bilibin, A.Yu ; Zabolotnyi, VV ; Kukkonen, VE ; Shelikh, A.F. / SYNTHESIS AND CHEMICAL-TRANSFORMATIONS OF ARYL-SUBSTITUTED POLY(BENZYLMETHACRYLATES. In: Journal of polymer science. Part B, Polymer letters. 1995 ; Vol. 37, сер.В, No. 1-2. pp. 43-46.
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abstract = "A series of poly(benzyl methacrylates) was prepared by radical polymerization of substituted benzyl esters of methacrylic acid. The polymers are X-ray amorphous, their M(n) are within the (4.7 - 6.2) 10(3) range, thus corresponding to the degree of polymerization of 23 - 30. Poly(benzyl methacrylates) were characterized using UV, IR, and NMR spectroscopy. The effect of substituents on the possibility of acid-catalyzed transformation of poly(benzyl methacrylates) into poly(methacrylic acid) is estimated.",
author = "A.Yu Bilibin and VV Zabolotnyi and VE Kukkonen and A.F. Shelikh",
year = "1995",
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volume = "37, сер.В",
pages = "43--46",
journal = "Journal of Polymer Science, Part B: Polymer Physics",
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SYNTHESIS AND CHEMICAL-TRANSFORMATIONS OF ARYL-SUBSTITUTED POLY(BENZYLMETHACRYLATES. / Bilibin, A.Yu; Zabolotnyi, VV; Kukkonen, VE; Shelikh, A.F.

In: Journal of polymer science. Part B, Polymer letters, Vol. 37, сер.В, No. 1-2, 1995, p. 43-46.

Research output

TY - JOUR

T1 - SYNTHESIS AND CHEMICAL-TRANSFORMATIONS OF ARYL-SUBSTITUTED POLY(BENZYLMETHACRYLATES

AU - Bilibin, A.Yu

AU - Zabolotnyi, VV

AU - Kukkonen, VE

AU - Shelikh, A.F.

PY - 1995

Y1 - 1995

N2 - A series of poly(benzyl methacrylates) was prepared by radical polymerization of substituted benzyl esters of methacrylic acid. The polymers are X-ray amorphous, their M(n) are within the (4.7 - 6.2) 10(3) range, thus corresponding to the degree of polymerization of 23 - 30. Poly(benzyl methacrylates) were characterized using UV, IR, and NMR spectroscopy. The effect of substituents on the possibility of acid-catalyzed transformation of poly(benzyl methacrylates) into poly(methacrylic acid) is estimated.

AB - A series of poly(benzyl methacrylates) was prepared by radical polymerization of substituted benzyl esters of methacrylic acid. The polymers are X-ray amorphous, their M(n) are within the (4.7 - 6.2) 10(3) range, thus corresponding to the degree of polymerization of 23 - 30. Poly(benzyl methacrylates) were characterized using UV, IR, and NMR spectroscopy. The effect of substituents on the possibility of acid-catalyzed transformation of poly(benzyl methacrylates) into poly(methacrylic acid) is estimated.

M3 - статья

VL - 37, сер.В

SP - 43

EP - 46

JO - Journal of Polymer Science, Part B: Polymer Physics

JF - Journal of Polymer Science, Part B: Polymer Physics

SN - 0887-6266

IS - 1-2

ER -