Synthesis and Characterization of Barium Amidoborane

Research outputpeer-review

Abstract

Barium amidoborane was synthesized for the first time by the reaction of metal barium with ammonia borane. The compound was characterized by the methods of the solid-phase 11B NMR and IR spectroscopy and elemental analysis. It was shown by simultaneous thermal analysis that hydrogen is the only volatile product of barium amidoborane decomposition in the temperature range 50–240°C.

Original languageEnglish
Pages (from-to)2875-2877
Number of pages3
JournalRussian Journal of General Chemistry
Volume87
Issue number12
DOIs
Publication statusPublished - 1 Dec 2017

Scopus subject areas

  • Chemistry(all)

Cite this

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title = "Synthesis and Characterization of Barium Amidoborane",
abstract = "Barium amidoborane was synthesized for the first time by the reaction of metal barium with ammonia borane. The compound was characterized by the methods of the solid-phase 11B NMR and IR spectroscopy and elemental analysis. It was shown by simultaneous thermal analysis that hydrogen is the only volatile product of barium amidoborane decomposition in the temperature range 50–240°C.",
keywords = "amidoboranes, barium, IR spectroscopy, NMR spectroscopy",
author = "Shcherbina, {N. A.} and Kazakov, {I. V.} and Timoshkin, {A. Yu}",
year = "2017",
month = "12",
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language = "English",
volume = "87",
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Synthesis and Characterization of Barium Amidoborane. / Shcherbina, N. A.; Kazakov, I. V.; Timoshkin, A. Yu.

In: Russian Journal of General Chemistry, Vol. 87, No. 12, 01.12.2017, p. 2875-2877.

Research outputpeer-review

TY - JOUR

T1 - Synthesis and Characterization of Barium Amidoborane

AU - Shcherbina, N. A.

AU - Kazakov, I. V.

AU - Timoshkin, A. Yu

PY - 2017/12/1

Y1 - 2017/12/1

N2 - Barium amidoborane was synthesized for the first time by the reaction of metal barium with ammonia borane. The compound was characterized by the methods of the solid-phase 11B NMR and IR spectroscopy and elemental analysis. It was shown by simultaneous thermal analysis that hydrogen is the only volatile product of barium amidoborane decomposition in the temperature range 50–240°C.

AB - Barium amidoborane was synthesized for the first time by the reaction of metal barium with ammonia borane. The compound was characterized by the methods of the solid-phase 11B NMR and IR spectroscopy and elemental analysis. It was shown by simultaneous thermal analysis that hydrogen is the only volatile product of barium amidoborane decomposition in the temperature range 50–240°C.

KW - amidoboranes

KW - barium

KW - IR spectroscopy

KW - NMR spectroscopy

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DO - 10.1134/S1070363217120192

M3 - Letter

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JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

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