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Study on thermolysis process of a new hydrated and protonated perovskite-like oxides H2K0.5Bi2.5Ti4O13·yH2O. / Minich, Iana A.; Silyukov, Oleg I.; Kulish, Liliia D.; Zvereva, Irina A.

In: Ceramics International, Vol. 45, No. 2, 01.02.2019, p. 2704-2709.

Research output: Contribution to journal › Article › peer-review

Harvard

Minich, IA, Silyukov, OI, Kulish, LD & Zvereva, IA 2019, 'Study on thermolysis process of a new hydrated and protonated perovskite-like oxides H2K0.5Bi2.5Ti4O13·yH2O', Ceramics International, vol. 45, no. 2, pp. 2704-2709. https://doi.org/10.1016/j.ceramint.2018.10.004

APA

Minich, I. A., Silyukov, O. I., Kulish, L. D., & Zvereva, I. A. (2019). Study on thermolysis process of a new hydrated and protonated perovskite-like oxides H2K0.5Bi2.5Ti4O13·yH2O. Ceramics International, 45(2), 2704-2709. https://doi.org/10.1016/j.ceramint.2018.10.004

Vancouver

Minich IA, Silyukov OI, Kulish LD, Zvereva IA. Study on thermolysis process of a new hydrated and protonated perovskite-like oxides H2K0.5Bi2.5Ti4O13·yH2O. Ceramics International. 2019 Feb 1;45(2):2704-2709. https://doi.org/10.1016/j.ceramint.2018.10.004

Author

Minich, Iana A. ; Silyukov, Oleg I. ; Kulish, Liliia D. ; Zvereva, Irina A. / Study on thermolysis process of a new hydrated and protonated perovskite-like oxides H2K0.5Bi2.5Ti4O13·yH2O. In: Ceramics International. 2019 ; Vol. 45, No. 2. pp. 2704-2709.

BibTeX

@article{dfffe7e37dbb496ab9024c5eb4616c55,
title = "Study on thermolysis process of a new hydrated and protonated perovskite-like oxides H2K0.5Bi2.5Ti4O13·yH2O",
abstract = "A protonated form of the n = 4 layered bismuth containing perovskite-like titanate K2.5Bi2.5Ti4O13 belonging to Ruddlesden-Popper phases was prepared via ion exchange reaction of interlayer K+ with protons. Its composition was investigated by TG ICP and EDX analysis was found to be H2K0.5Bi2.5Ti4O13·H2O. The thermal behavior of the obtained phase was investigated by STA coupled with mass-spectrometry, the structural changes, happening with the sample during heating, were examined by XRD. It was shown that the as-prepared hydrated phase undergoes two-stage dehydration at low temperatures (up to 160 °C). The further heating leads to the gradual decomposition and crystallization of new phases, notably Bi2Ti2O7, Bi4Ti3O12 and Bi2Ti4O11. The morphology of the as-prepared sample and samples after heat treatment was examined using SEM.",
keywords = "A - Powders: solid-state reaction, C - Thermal properties, D - Perovskites, D - Transition metal oxides, Powders: solid-state reaction, LN, SERIES, Transition metal oxides, Perovskites, ION-EXCHANGE, INTERCALATION, Thermal properties, PHOTOCATALYTIC ACTIVITY, LA, ND, SM, LAYERED PEROVSKITES, RUDDLESDEN-POPPER PHASES",
author = "Minich, {Iana A.} and Silyukov, {Oleg I.} and Kulish, {Liliia D.} and Zvereva, {Irina A.}",
year = "2019",
month = feb,
day = "1",
doi = "10.1016/j.ceramint.2018.10.004",
language = "English",
volume = "45",
pages = "2704--2709",
journal = "Ceramics International",
issn = "0272-8842",
publisher = "Elsevier",
number = "2",

}

RIS

TY - JOUR

T1 - Study on thermolysis process of a new hydrated and protonated perovskite-like oxides H2K0.5Bi2.5Ti4O13·yH2O

AU - Minich, Iana A.

AU - Silyukov, Oleg I.

AU - Kulish, Liliia D.

AU - Zvereva, Irina A.

PY - 2019/2/1

Y1 - 2019/2/1

N2 - A protonated form of the n = 4 layered bismuth containing perovskite-like titanate K2.5Bi2.5Ti4O13 belonging to Ruddlesden-Popper phases was prepared via ion exchange reaction of interlayer K+ with protons. Its composition was investigated by TG ICP and EDX analysis was found to be H2K0.5Bi2.5Ti4O13·H2O. The thermal behavior of the obtained phase was investigated by STA coupled with mass-spectrometry, the structural changes, happening with the sample during heating, were examined by XRD. It was shown that the as-prepared hydrated phase undergoes two-stage dehydration at low temperatures (up to 160 °C). The further heating leads to the gradual decomposition and crystallization of new phases, notably Bi2Ti2O7, Bi4Ti3O12 and Bi2Ti4O11. The morphology of the as-prepared sample and samples after heat treatment was examined using SEM.

AB - A protonated form of the n = 4 layered bismuth containing perovskite-like titanate K2.5Bi2.5Ti4O13 belonging to Ruddlesden-Popper phases was prepared via ion exchange reaction of interlayer K+ with protons. Its composition was investigated by TG ICP and EDX analysis was found to be H2K0.5Bi2.5Ti4O13·H2O. The thermal behavior of the obtained phase was investigated by STA coupled with mass-spectrometry, the structural changes, happening with the sample during heating, were examined by XRD. It was shown that the as-prepared hydrated phase undergoes two-stage dehydration at low temperatures (up to 160 °C). The further heating leads to the gradual decomposition and crystallization of new phases, notably Bi2Ti2O7, Bi4Ti3O12 and Bi2Ti4O11. The morphology of the as-prepared sample and samples after heat treatment was examined using SEM.

KW - A - Powders: solid-state reaction

KW - C - Thermal properties

KW - D - Perovskites

KW - D - Transition metal oxides

KW - Powders: solid-state reaction

KW - LN

KW - SERIES

KW - Transition metal oxides

KW - Perovskites

KW - ION-EXCHANGE

KW - INTERCALATION

KW - Thermal properties

KW - PHOTOCATALYTIC ACTIVITY

KW - LA

KW - ND

KW - SM

KW - LAYERED PEROVSKITES

KW - RUDDLESDEN-POPPER PHASES

UR - http://www.scopus.com/inward/record.url?scp=85054452086&partnerID=8YFLogxK

UR - http://www.mendeley.com/research/study-thermolysis-process-new-hydrated-protonated-perovskitelike-oxides-h2k05bi25ti4o13yh2o

U2 - 10.1016/j.ceramint.2018.10.004

DO - 10.1016/j.ceramint.2018.10.004

M3 - Article

AN - SCOPUS:85054452086

VL - 45

SP - 2704

EP - 2709

JO - Ceramics International

JF - Ceramics International

SN - 0272-8842

IS - 2

ER -

ID: 37015281