Study of structural order in porphyrin-fullerene dyad zndhd6ee monolayers by electron diffraction and atomic force microscopy. / D'yakova, Yu A.; Suvorova, E. I.; Orekhov, Andrei S.; Orekhov, Anton S.; Alekseev, A. S.; Gainutdinov, R. V.; Klechkovskaya, V. V.; Tereschenko, E. Yu; Tkachenko, N. V.; Lemmetyinen, H.; Feigin, L. A.; Kovalchuk, M. V.
In: Crystallography Reports, Vol. 58, No. 6, 11.2013, p. 927-933.Research output: Contribution to journal › Article › peer-review
}
TY - JOUR
T1 - Study of structural order in porphyrin-fullerene dyad zndhd6ee monolayers by electron diffraction and atomic force microscopy
AU - D'yakova, Yu A.
AU - Suvorova, E. I.
AU - Orekhov, Andrei S.
AU - Orekhov, Anton S.
AU - Alekseev, A. S.
AU - Gainutdinov, R. V.
AU - Klechkovskaya, V. V.
AU - Tereschenko, E. Yu
AU - Tkachenko, N. V.
AU - Lemmetyinen, H.
AU - Feigin, L. A.
AU - Kovalchuk, M. V.
N1 - Funding Information: ACKNOWLEDGMENTS This study was supported in part by the Ministry of Education and Science of the Russian Federation (state contract no. 02.527.12.0004) and Grant NSh 5837.2012.2 for Support of Leading Scientific Schools.
PY - 2013/11
Y1 - 2013/11
N2 - The structure of porphyrin-fullerene dyad ZnDHD6ee monolayers formed on the surface of aqueous subphase in a Langmuir trough and transferred onto solid substrates has been studied. The data obtained are interpreted using simulation of the structure of isolated molecules and their packing in mono- layer and modeling of diffraction patterns from molecular aggregates having different sizes and degrees of order. Experiments on the formation of condensed ZnDHD6ee monolayers are described. The structure of these monolayers on a water surface is analyzed using ?-A isotherms. The structure of the monolayers trans- ferred onto solid substrates is investigated by electron diffraction and atomic force microscopy. The unit-cell parameters of two-dimensional domains, which are characteristic of molecular packing in monolayers and deposited films, are determined. Domains are found to be organized into a texture (the molecular axes are oriented by the [001] direction perpendicular to the substrate). The monolayers contain a limited number of small 3D domains.
AB - The structure of porphyrin-fullerene dyad ZnDHD6ee monolayers formed on the surface of aqueous subphase in a Langmuir trough and transferred onto solid substrates has been studied. The data obtained are interpreted using simulation of the structure of isolated molecules and their packing in mono- layer and modeling of diffraction patterns from molecular aggregates having different sizes and degrees of order. Experiments on the formation of condensed ZnDHD6ee monolayers are described. The structure of these monolayers on a water surface is analyzed using ?-A isotherms. The structure of the monolayers trans- ferred onto solid substrates is investigated by electron diffraction and atomic force microscopy. The unit-cell parameters of two-dimensional domains, which are characteristic of molecular packing in monolayers and deposited films, are determined. Domains are found to be organized into a texture (the molecular axes are oriented by the [001] direction perpendicular to the substrate). The monolayers contain a limited number of small 3D domains.
UR - http://www.scopus.com/inward/record.url?scp=84902489245&partnerID=8YFLogxK
U2 - 10.1134/S1063774513060096
DO - 10.1134/S1063774513060096
M3 - Article
AN - SCOPUS:84902489245
VL - 58
SP - 927
EP - 933
JO - Crystallography Reports
JF - Crystallography Reports
SN - 1063-7745
IS - 6
ER -
ID: 88208185