Structure, optical, and electrochemical properties of cyclometalated iridium complexes with 2-phenylbenzothiazol, N-(benzothiazole)-N-idoacetamidinate, and N-(thiazole)-N-idoacetamidinate ions

E.A. Katlenok, A.A. Zolotarev, A.Y. Ivanov, S.N. Smirnov, R.I. Baichurin, K.P. Balashev

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Abstract

© 2015 Pleiades Publishing, Ltd.Nucleophilic addition of benzothiazole-2-amine and thiazole-2-amine to acetonitrile bound to iridium in a cyclometalated complex have been discovered. Cis-structure of the iridium complexes with bis{(2-phenyl-3-ido)benzothiazole)[N-(benzothiazole)-N-idoacetamidinate]} and bis{2-phenyl-3-ido)benzothiazole)-[N-(thiazole)-N-idoacetamidinate]} both in crystal and in solution have been proved by X-ray diffraction analysis as well as 1H, 13C, 15N NMR, and IR spectroscopy.
Original languageEnglish
Pages (from-to)2634-2641
JournalRussian Journal of General Chemistry
Issue number11
DOIs
Publication statusPublished - 2015

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