Standard

Structural role of aluminum in the (0.8-x)LiF · xNaF-0.2Al(PO3)3 glasses. / Sokolov, I. A.; Tarlakov, Yu P.; Murin, I. V.; Pronkin, A. A.

In: Glass Physics and Chemistry, Vol. 25, No. 1, 01.1999, p. 75-82.

Research output: Contribution to journal › Article › peer-review

Harvard

Sokolov, IA, Tarlakov, YP, Murin, IV & Pronkin, AA 1999, 'Structural role of aluminum in the (0.8-x)LiF · xNaF-0.2Al(PO3)3 glasses', Glass Physics and Chemistry, vol. 25, no. 1, pp. 75-82.

APA

Sokolov, I. A., Tarlakov, Y. P., Murin, I. V., & Pronkin, A. A. (1999). Structural role of aluminum in the (0.8-x)LiF · xNaF-0.2Al(PO3)3 glasses. Glass Physics and Chemistry, 25(1), 75-82.

Vancouver

Sokolov IA, Tarlakov YP, Murin IV, Pronkin AA. Structural role of aluminum in the (0.8-x)LiF · xNaF-0.2Al(PO3)3 glasses. Glass Physics and Chemistry. 1999 Jan;25(1):75-82.

Author

Sokolov, I. A. ; Tarlakov, Yu P. ; Murin, I. V. ; Pronkin, A. A. / Structural role of aluminum in the (0.8-x)LiF · xNaF-0.2Al(PO3)3 glasses. In: Glass Physics and Chemistry. 1999 ; Vol. 25, No. 1. pp. 75-82.

BibTeX

@article{450330b3586142f19126be703acd2178,
title = "Structural role of aluminum in the (0.8-x)LiF · xNaF-0.2Al(PO3)3 glasses",
abstract = "The structural role of aluminum upon replacement of lithium cations by sodium cations in the (0.8-x)LiF · xNaF-0.2Al(PO3)3 glasses is investigated by X-ray photoelectron and IR spectroscopies. It is shown that the equimolecular substitution of sodium for lithium is accompanied by changes in the coordination number of aluminum (Al(VI)→Al(IV)). The extrema observed in the concentration dependences Eσ=f(βNa) and logσ=f(βNa) (where βNa = [Na]/([Na] + [Li])) are interpreted from the viewpoint of selective interaction between the glass components during the exchange reactions in the course of glass synthesis. It is demonstrated that the physicochemical properties of glasses are determined by the properties of different structural-chemical units produced during the glass synthesis, as well as by the concentration ratio of these units.",
author = "Sokolov, {I. A.} and Tarlakov, {Yu P.} and Murin, {I. V.} and Pronkin, {A. A.}",
year = "1999",
month = jan,
language = "English",
volume = "25",
pages = "75--82",
journal = "Glass Physics and Chemistry",
issn = "1087-6596",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "1",

}

RIS

TY - JOUR

T1 - Structural role of aluminum in the (0.8-x)LiF · xNaF-0.2Al(PO3)3 glasses

AU - Sokolov, I. A.

AU - Tarlakov, Yu P.

AU - Murin, I. V.

AU - Pronkin, A. A.

PY - 1999/1

Y1 - 1999/1

N2 - The structural role of aluminum upon replacement of lithium cations by sodium cations in the (0.8-x)LiF · xNaF-0.2Al(PO3)3 glasses is investigated by X-ray photoelectron and IR spectroscopies. It is shown that the equimolecular substitution of sodium for lithium is accompanied by changes in the coordination number of aluminum (Al(VI)→Al(IV)). The extrema observed in the concentration dependences Eσ=f(βNa) and logσ=f(βNa) (where βNa = [Na]/([Na] + [Li])) are interpreted from the viewpoint of selective interaction between the glass components during the exchange reactions in the course of glass synthesis. It is demonstrated that the physicochemical properties of glasses are determined by the properties of different structural-chemical units produced during the glass synthesis, as well as by the concentration ratio of these units.

AB - The structural role of aluminum upon replacement of lithium cations by sodium cations in the (0.8-x)LiF · xNaF-0.2Al(PO3)3 glasses is investigated by X-ray photoelectron and IR spectroscopies. It is shown that the equimolecular substitution of sodium for lithium is accompanied by changes in the coordination number of aluminum (Al(VI)→Al(IV)). The extrema observed in the concentration dependences Eσ=f(βNa) and logσ=f(βNa) (where βNa = [Na]/([Na] + [Li])) are interpreted from the viewpoint of selective interaction between the glass components during the exchange reactions in the course of glass synthesis. It is demonstrated that the physicochemical properties of glasses are determined by the properties of different structural-chemical units produced during the glass synthesis, as well as by the concentration ratio of these units.

UR - http://www.scopus.com/inward/record.url?scp=0033239382&partnerID=8YFLogxK

M3 - Article

AN - SCOPUS:0033239382

VL - 25

SP - 75

EP - 82

JO - Glass Physics and Chemistry

JF - Glass Physics and Chemistry

SN - 1087-6596

IS - 1

ER -

ID: 88059868