DOI

  • I. M. Grigoriev
  • R. Le Doucen
  • J. Boissoles
  • B. Calil
  • C. Boulet
  • J. M. Hartmann
  • X. Bruet
  • M. L. Dubernet

The test of an interaction potential for HF-argon recently determined from the spectroscopy of the Van der Waals complex requires accurate experimental widths and shifts cross sections. Since inconsistencies existed between previous measurements, collisional lineshapes were studied at T = 296 K by high-resolution Fourier transform spectroscopy for the 0-0, 0-1, and 0-2 bands. The accurate close-coupling molecular scattering calculations of Green and Hutson (1994. J. Chem. Phys. 100, 891) were extended to a complementary set of kinetic energies in order to check the thermal averaging procedure. Agreement between measured and computed room temperature cross sections is excellent for the three vibrational bands. This confirms the accuracy of the HF-argon surface and particularly its dependence on the HF vibrational level, which is sensitively probed both by the widths and by the shifts cross sections at high ji values.

Original languageEnglish
Pages (from-to)249-256
Number of pages8
JournalJournal of Molecular Spectroscopy
Volume198
Issue number2
DOIs
StatePublished - 1 Jan 1999

    Scopus subject areas

  • Atomic and Molecular Physics, and Optics
  • Spectroscopy
  • Physical and Theoretical Chemistry

    Research areas

  • Fourier transform spectroscopy, HF in a bath of argon, Widths and shifts

ID: 28687786