Site- and spin-dependent coupling at the highly ordered h-BN/Co(0001) interface

Дмитрий Юрьевич Усачев, Артем Вячеславович Тарасов, Кирилл Андреевич Бокай, Виктор Олегович Шевелев, Олег Юрьевич Вилков, Анатолий Евгеньевич Петухов, Артем Геннадиевич Рыбкин, Ilya I. Ogorodnikov, Mikhail V. Kuznetsov, Matthias Muntwiler, Fumihiko Matsui, Lada V. Yashina, Clemens Laubschat, Denis V. Vyalikh

Research output

9 Citations (Scopus)


Using photoelectron diffraction and spectroscopy, we explore the structural and electronic properties of the hexagonal boron nitride (h-BN) monolayer epitaxially grown on the Co(0001) surface. Perfect matching of the lattice parameters allows formation of a well-defined interface where the B atoms occupy the hollow sites while the N atoms are located above the Co atoms. The corrugation of the h-BN monolayer and its distance from the substrate were determined by means of R-factor analysis. The obtained results are in perfect agreement with the density functional theory (DFT) predictions. The electronic structure of the interface is characterized by a significant mixing of the h-BN and Co states. Such hybridized states appear in the h-BN band gap. This allows to obtain atomically resolved scanning tunneling microscopy (STM) images from the formally insulating 2D material being in contact with ferromagnetic metal. The STM images reveal mainly the nitrogen sublattice due to a dominating contribution of nitrogen orbitals to the electronic states at the Fermi level. We believe that the high quality, well-defined structure and interesting electronic properties make the h-BN/Co(0001) interface suitable for spintronic applications.

Original languageEnglish
Article number195438
Number of pages10
JournalPhysical Review B
Issue number19
Publication statusPublished - 26 Nov 2018

Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Condensed Matter Physics

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