TY - JOUR

T1 - Seasonal Cycle of the Total Ozone Content over Southern High Latitudes in the CCM SOCOLv3

AU - Иманова, Анастасия Сергеевна

AU - Egorova, T.

AU - Зубов, Владимир Аркадьевич

AU - Миронов, Андрей Дмитриевич

AU - Поляков, Александр Викторович

AU - Неробелов, Георгий Максимович

AU - Розанов, Евгений Владимирович

PY - 2025/10/9

Y1 - 2025/10/9

N2 - The severe ozone depletion over the Southern polar region, known as the “ozone hole,” is a stark example of global ozone depletion caused by human-made chemicals. This has implications for climate change and increased harmful surface solar UV. Several Chemistry–Climate models (CCMs) tend to underestimate total column ozone (TCO) against satellite measurements over the Southern polar region. This underestimation can reach up to 50% in monthly mean zonally averaged biases during cold seasons. The most significant discrepancies were found in the CCM SOlar Climate Ozone Links version 3 (SOCOLv3). We use SOCOLv3 to study the sensitivity of Antarctic TCO to three key factors: (1) stratospheric heterogeneous reaction efficiency, (2) meridional flux intensity into polar regions from sub-grid scale mixing, and (3) photodissociation rate calculation accuracy. We compared the model results with satellite data from Infrared Fourier Spectrometer-2 (IKFS-2), Microwave Limb Sounder (MLS), and Michelson Interferometer for Passive Atmospheric Sounding (MIPAS). The most effective processes for improving polar ozone simulation are photolysis and horizontal mixing. Increasing horizontal mixing improves the simulated TCO seasonal cycle but negatively impacts CH4 and N2O distributions. Using the Cloud-J v.8.0 photolysis module has improved photolysis rate calculations and the seasonal ozone cycle representation over the Southern polar region. This paper outlines how different processes impact chemistry–climate model performance in the southern polar stratosphere, with potential implications for future advancements.

AB - The severe ozone depletion over the Southern polar region, known as the “ozone hole,” is a stark example of global ozone depletion caused by human-made chemicals. This has implications for climate change and increased harmful surface solar UV. Several Chemistry–Climate models (CCMs) tend to underestimate total column ozone (TCO) against satellite measurements over the Southern polar region. This underestimation can reach up to 50% in monthly mean zonally averaged biases during cold seasons. The most significant discrepancies were found in the CCM SOlar Climate Ozone Links version 3 (SOCOLv3). We use SOCOLv3 to study the sensitivity of Antarctic TCO to three key factors: (1) stratospheric heterogeneous reaction efficiency, (2) meridional flux intensity into polar regions from sub-grid scale mixing, and (3) photodissociation rate calculation accuracy. We compared the model results with satellite data from Infrared Fourier Spectrometer-2 (IKFS-2), Microwave Limb Sounder (MLS), and Michelson Interferometer for Passive Atmospheric Sounding (MIPAS). The most effective processes for improving polar ozone simulation are photolysis and horizontal mixing. Increasing horizontal mixing improves the simulated TCO seasonal cycle but negatively impacts CH4 and N2O distributions. Using the Cloud-J v.8.0 photolysis module has improved photolysis rate calculations and the seasonal ozone cycle representation over the Southern polar region. This paper outlines how different processes impact chemistry–climate model performance in the southern polar stratosphere, with potential implications for future advancements.

KW - chemistry-climate models

KW - horizontal transport

KW - ozone layer

KW - photolysis rate

KW - stratospheric chemistry

UR - https://www.mendeley.com/catalogue/6d86c55f-2415-3dd4-acd1-2103b019077e/

U2 - 10.3390/atmos16101172

DO - 10.3390/atmos16101172

M3 - Article

VL - 16

JO - ATMOSPHERE

JF - ATMOSPHERE

SN - 1598-3560

IS - 10

M1 - 1172

ER -