Rule, Not Exclusion: Formation of Dichlorine-Containing Supramolecular Complexes with Chlorometalates(IV)

Andrey N. Usoltsev, Nikita A. Korobeynikov, Boris A. Kolesov, Alexander S. Novikov, Denis G. Samsonenko, Vladimir P. Fedin, Maxim N. Sokolov, Sergey A. Adonin

Research output: Contribution to journalArticlepeer-review

3 Scopus citations

Abstract

Supramolecular derivatives of chlorostannate(IV) and -plumbate(IV) with {Cl2} units, Cat2{[MCl6](Cl2)x} (1-5; M = Sn, Pb, cat = 1-methylpyridinium (1-MePy), tetramethylammonium (TMA)) were prepared and characterized by X-ray diffractometry and Raman spectroscopy. In particular, the TMA-containing complexes demonstrate remarkable thermal stability, releasing Cl2 only at elevated temperatures.

Original languageEnglish
Pages (from-to)4171-4177
Number of pages7
JournalInorganic Chemistry
Volume60
Issue number6
DOIs
StatePublished - 15 Mar 2021

Scopus subject areas

  • Physical and Theoretical Chemistry
  • Inorganic Chemistry

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