[Re(CO)3(bipy)(ClO4)]: Synthesis in a Proton-Donor Solvent, Crystal, and Molecular Structure

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Abstract

Abstract: The complex [Re(CO)3(bipy)(ClO4)] (bipy = 2,2ʹ-bipyridine) was prepared by the reaction of [Re(CO)3(H2O,EtOH)3](ClO4) with bipy in aqueous ethanol, followed by crystallization from dichloromethane. The composition and structure of the complex were determined by single crystal X-ray diffraction analysis. The complex has a molecular octahedral structure with bidentate coordination of bipy and inner-sphere monodentate coordination of perchlorate ion in the fac-position to bipy. The complex was also characterized by IR and UV-visible absorption spectroscopy.

Original languageEnglish
Pages (from-to)2333-2337
Number of pages5
JournalRussian Journal of General Chemistry
Volume90
Issue number12
DOIs
StatePublished - 25 Dec 2020

Scopus subject areas

  • Chemistry(all)

Keywords

  • bipyridine complexes
  • perchlorate complexes
  • rhenium tricarbonyl complexes
  • single crystal X-ray diffraction analysis

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