Reassembled Nanosheets of Layered Perovskite-Like Niobate HCa2Nb3O10 as Photocatalysts for Hydrogen Production from Aqueous Solutions of Plant Biomass Processing Products

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Reassembled Nanosheets of Layered Perovskite-Like Niobate HCa2Nb3O10 as Photocatalysts for Hydrogen Production from Aqueous Solutions of Plant Biomass Processing Products. / Kurnosenko, S.A.; Silyukov, O.I.; Rodionov, I.A.; Minich, Ya.A.; Ustinova, A.I.; Zvereva, I.A.

In: Kinetics and Catalysis, Vol. 65, No. 5, 22.10.2024, p. 586-596.

Research output: Contribution to journal › Article › peer-review

BibTeX

@article{2e4afb3b1e3143468b384cde86b8eb89,

title = "Reassembled Nanosheets of Layered Perovskite-Like Niobate HCa2Nb3O10 as Photocatalysts for Hydrogen Production from Aqueous Solutions of Plant Biomass Processing Products",

abstract = "In conditions of depletion of mineral reserves, plant biomass is considered a renewable natural resource that can be photocatalytically processed to produce energy-intensive and environmentally friendly hydrogen fuel. In this regard, the present article focuses on the improvement of photocatalytic activity of thelayered perovskite-structured niobate HCa2Nb3O10 in the reactions of hydrogen production from aqueous solutions of typical plant biomass components, glucose and xylose, via its exfoliation into nanosheets followed by their reassembly and modification with a Pt cocatalyst. The reassembled compound obtained was shown to outperform in the activity the initial niobate and reference photocatalyst TiO2 P25 Degussa up to6.3 and 5.3 times, respectively, providing a hydrogen production rate up to 24.2 mmol h−1g−1 and apparent quantum efficiency up to 10% in the mid-near ultraviolet range.",

keywords = "фотокатализ, получение водорода, растительная биомасса, нанолисты перовскита, отслаивание, пересборка, photocatalysis, hydrogen, plant biomass, perovskite nanosheets, exfoliation, reassembly, perovskite nanosheets, exfoliation, plant biomass, hydrogen, reassembly, photocatalysis",

author = "S.A. Kurnosenko and O.I. Silyukov and I.A. Rodionov and Ya.A. Minich and A.I. Ustinova and I.A. Zvereva",

note = "S. A. Kurnosenko, O. I. Silyukov, I. A. Rodionov, I. A. Minich, A. I. Ustinovа, and I. A. Zvereva, Reassembled Nanosheets of Layered Perovskite-Like Niobate HCa2Nb3O10 as Photocatalysts for Hydrogen Production from Aqueous Solutions of Plant Biomass Processing Products.Kinetics and Catalysis, 2024, 65(5) 586–596. ",

year = "2024",

month = oct,

day = "22",

doi = "10.1134/s0023158424601943",

language = "English",

volume = "65",

pages = "586--596",

journal = "Kinetics and Catalysis",

issn = "0023-1584",

publisher = "МАИК {"}Наука/Интерпериодика{"}",

number = "5",

}

RIS

TY - JOUR

T1 - Reassembled Nanosheets of Layered Perovskite-Like Niobate HCa2Nb3O10 as Photocatalysts for Hydrogen Production from Aqueous Solutions of Plant Biomass Processing Products

AU - Kurnosenko, S.A.

AU - Silyukov, O.I.

AU - Rodionov, I.A.

AU - Minich, Ya.A.

AU - Ustinova, A.I.

AU - Zvereva, I.A.

N1 - S. A. Kurnosenko, O. I. Silyukov, I. A. Rodionov, I. A. Minich, A. I. Ustinovа, and I. A. Zvereva, Reassembled Nanosheets of Layered Perovskite-Like Niobate HCa2Nb3O10 as Photocatalysts for Hydrogen Production from Aqueous Solutions of Plant Biomass Processing Products.Kinetics and Catalysis, 2024, 65(5) 586–596.

PY - 2024/10/22

Y1 - 2024/10/22

N2 - In conditions of depletion of mineral reserves, plant biomass is considered a renewable natural resource that can be photocatalytically processed to produce energy-intensive and environmentally friendly hydrogen fuel. In this regard, the present article focuses on the improvement of photocatalytic activity of thelayered perovskite-structured niobate HCa2Nb3O10 in the reactions of hydrogen production from aqueous solutions of typical plant biomass components, glucose and xylose, via its exfoliation into nanosheets followed by their reassembly and modification with a Pt cocatalyst. The reassembled compound obtained was shown to outperform in the activity the initial niobate and reference photocatalyst TiO2 P25 Degussa up to6.3 and 5.3 times, respectively, providing a hydrogen production rate up to 24.2 mmol h−1g−1 and apparent quantum efficiency up to 10% in the mid-near ultraviolet range.

AB - In conditions of depletion of mineral reserves, plant biomass is considered a renewable natural resource that can be photocatalytically processed to produce energy-intensive and environmentally friendly hydrogen fuel. In this regard, the present article focuses on the improvement of photocatalytic activity of thelayered perovskite-structured niobate HCa2Nb3O10 in the reactions of hydrogen production from aqueous solutions of typical plant biomass components, glucose and xylose, via its exfoliation into nanosheets followed by their reassembly and modification with a Pt cocatalyst. The reassembled compound obtained was shown to outperform in the activity the initial niobate and reference photocatalyst TiO2 P25 Degussa up to6.3 and 5.3 times, respectively, providing a hydrogen production rate up to 24.2 mmol h−1g−1 and apparent quantum efficiency up to 10% in the mid-near ultraviolet range.

KW - фотокатализ, получение водорода, растительная биомасса, нанолисты перовскита, отслаивание, пересборка

KW - photocatalysis, hydrogen, plant biomass, perovskite nanosheets, exfoliation, reassembly

KW - perovskite nanosheets

KW - exfoliation

KW - plant biomass

KW - hydrogen

KW - reassembly

KW - photocatalysis

UR - https://www.mendeley.com/catalogue/fed2471e-036d-3b4d-91ad-72352843b3fa/

U2 - 10.1134/s0023158424601943

DO - 10.1134/s0023158424601943

M3 - Article

VL - 65

SP - 586

EP - 596

JO - Kinetics and Catalysis

JF - Kinetics and Catalysis

SN - 0023-1584

IS - 5

ER -

ID: 126360226