Reactions of rhodium carbonyl clusters with heterobidentate ligands. Synthesis and structural characterization of the Rh6(CO) 15[(C6H5)2PC6H 4N(CH3)2] cluster compounds

E. V. Gracheva, G. Linti

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4 Citations (Scopus)

Abstract

The reaction of heterobidentate 4-(dimethylamino)phenyldiphenylphosphine with labile cluster Rh6(CO)15(NCMe) yielding a new monosubstituted cluster Rh6(CO)15(Ph2PC 6H4NMe2) was described. The reactions of the resulting cluster with GaX3 compounds were studied. The structure of all obtained compounds was completely characterized both in a solid phase and in a solution by X-ray diffraction analysis, mass spectrometry, and IR and polynuclear NMR spectroscopy.

Original languageEnglish
Pages (from-to)414-422
Number of pages9
JournalRussian Journal of General Chemistry
Volume80
Issue number3
DOIs
Publication statusPublished - 1 Mar 2010

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Scopus subject areas

  • Chemistry(all)

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