Reaction of chiral pyrrolylphosphine with polynuclear carbonyl complexes of osmium and rhodium

V. I. Ponomarenko, E. V. Gracheva, I. O. Koshevoi, V. A. Gindin, S. P. Tunik, I. Pursiainen, M. Haukka

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Abstract

Reactions of labile Os3(CO)10(NCMe)2 and Rh6(CO)15(NCMe) clusters and dinuclear Rh 2(CO)4Cl2 complex with chiral (S)-[2-(4-isopropyl-4,5-dihydro-1,3-oxazol-2-yl)phenyl]di(1H-pyrrol-1-yl) phosphine were studied. The reaction of Os3(CO)10(NCMe) 2 with the chiral phosphine was diastereoselective, and it afforded only one diastereoisomer with ee 100%. All isolated compounds were completely characterized by NMR and mass spectra and X-ray diffraction data.

Original languageEnglish
Pages (from-to)408-413
Number of pages6
JournalRussian Journal of General Chemistry
Volume80
Issue number3
DOIs
Publication statusPublished - 1 Mar 2010

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Scopus subject areas

  • Chemistry(all)

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