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Phase Equilibria in Alcohol–Ester Systems with Deep Eutectic Solvents Based on Choline Chloride at 293.15 and 313.15 K. / Samarov, A. A.; Toikka, M. A.; Toikka, A. M.

In: Theoretical Foundations of Chemical Engineering, Vol. 55, No. 2, 01.03.2021, p. 290-300.

Research output: Contribution to journal › Article › peer-review

Harvard

Samarov, AA, Toikka, MA & Toikka, AM 2021, 'Phase Equilibria in Alcohol–Ester Systems with Deep Eutectic Solvents Based on Choline Chloride at 293.15 and 313.15 K', Theoretical Foundations of Chemical Engineering, vol. 55, no. 2, pp. 290-300. https://doi.org/10.1134/s004057952102010x

APA

Samarov, A. A., Toikka, M. A., & Toikka, A. M. (2021). Phase Equilibria in Alcohol–Ester Systems with Deep Eutectic Solvents Based on Choline Chloride at 293.15 and 313.15 K. Theoretical Foundations of Chemical Engineering, 55(2), 290-300. https://doi.org/10.1134/s004057952102010x

Vancouver

Samarov AA, Toikka MA, Toikka AM. Phase Equilibria in Alcohol–Ester Systems with Deep Eutectic Solvents Based on Choline Chloride at 293.15 and 313.15 K. Theoretical Foundations of Chemical Engineering. 2021 Mar 1;55(2):290-300. https://doi.org/10.1134/s004057952102010x

Author

Samarov, A. A. ; Toikka, M. A. ; Toikka, A. M. / Phase Equilibria in Alcohol–Ester Systems with Deep Eutectic Solvents Based on Choline Chloride at 293.15 and 313.15 K. In: Theoretical Foundations of Chemical Engineering. 2021 ; Vol. 55, No. 2. pp. 290-300.

BibTeX

@article{8968fa9943464dedb22c2644a67f187d,
title = "Phase Equilibria in Alcohol–Ester Systems with Deep Eutectic Solvents Based on Choline Chloride at 293.15 and 313.15 K",
abstract = "Liquid-liquid phase equilibria in ethanol-n-propyl acetate and n-propanol-ethyl acetate systems with deep eutectic solvents (DESs) at temperatures of 293.15 and 313.15 K and atmospheric pressure have been studied. DESs based on choline chloride, namely, choline chloride-glycerol and choline chloride-urea at a molar ratio of 1 : 2, have been investigated. An internal consistency check for experimental data has been performed using the Othmer-Tobias equation. Based on the data, the distribution coefficients and the values of selectivity have been calculated. The effect of an alcohol and an ester on the position of the region of phase equilibrium has been found. The nonrandom two-liquid (NRTL) model has been used to correlate experimental data on liquid-liquid equilibria.",
keywords = "choline chloride, deep eutectic solvents, liquid–liquid equilibria, NRTL model, liquid-liquid equilibria, EXTRACTION, LIQUID-LIQUID EQUILIBRIUM, MEDIA, SEPARATION",
author = "Samarov, {A. A.} and Toikka, {M. A.} and Toikka, {A. M.}",
note = "Publisher Copyright: {\textcopyright} 2021, Pleiades Publishing, Ltd.",
year = "2021",
month = mar,
day = "1",
doi = "10.1134/s004057952102010x",
language = "English",
volume = "55",
pages = "290--300",
journal = "Theoretical Foundations of Chemical Engineering",
issn = "0040-5795",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "2",

}

RIS

TY - JOUR

T1 - Phase Equilibria in Alcohol–Ester Systems with Deep Eutectic Solvents Based on Choline Chloride at 293.15 and 313.15 K

AU - Samarov, A. A.

AU - Toikka, M. A.

AU - Toikka, A. M.

N1 - Publisher Copyright: © 2021, Pleiades Publishing, Ltd.

PY - 2021/3/1

Y1 - 2021/3/1

N2 - Liquid-liquid phase equilibria in ethanol-n-propyl acetate and n-propanol-ethyl acetate systems with deep eutectic solvents (DESs) at temperatures of 293.15 and 313.15 K and atmospheric pressure have been studied. DESs based on choline chloride, namely, choline chloride-glycerol and choline chloride-urea at a molar ratio of 1 : 2, have been investigated. An internal consistency check for experimental data has been performed using the Othmer-Tobias equation. Based on the data, the distribution coefficients and the values of selectivity have been calculated. The effect of an alcohol and an ester on the position of the region of phase equilibrium has been found. The nonrandom two-liquid (NRTL) model has been used to correlate experimental data on liquid-liquid equilibria.

AB - Liquid-liquid phase equilibria in ethanol-n-propyl acetate and n-propanol-ethyl acetate systems with deep eutectic solvents (DESs) at temperatures of 293.15 and 313.15 K and atmospheric pressure have been studied. DESs based on choline chloride, namely, choline chloride-glycerol and choline chloride-urea at a molar ratio of 1 : 2, have been investigated. An internal consistency check for experimental data has been performed using the Othmer-Tobias equation. Based on the data, the distribution coefficients and the values of selectivity have been calculated. The effect of an alcohol and an ester on the position of the region of phase equilibrium has been found. The nonrandom two-liquid (NRTL) model has been used to correlate experimental data on liquid-liquid equilibria.

KW - choline chloride

KW - deep eutectic solvents

KW - liquid–liquid equilibria

KW - NRTL model

KW - liquid-liquid equilibria

KW - EXTRACTION

KW - LIQUID-LIQUID EQUILIBRIUM

KW - MEDIA

KW - SEPARATION

UR - http://www.scopus.com/inward/record.url?scp=85106871339&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/c53ac813-9dd4-3b01-a440-bed2d02f2299/

U2 - 10.1134/s004057952102010x

DO - 10.1134/s004057952102010x

M3 - Article

AN - SCOPUS:85106871339

VL - 55

SP - 290

EP - 300

JO - Theoretical Foundations of Chemical Engineering

JF - Theoretical Foundations of Chemical Engineering

SN - 0040-5795

IS - 2

ER -

ID: 87678481