Abstract

An isoquinolinium-pyrrole donor–acceptor dyad was found to exhibit photocatalytic activity in oxygen-to-peroxide photoreduction with oxalate as a sacrificial electron donor. The concentration of hydrogen peroxide was shown to reach a plateau of 0.57 mM. The screening of related pyridinium-pyrrole dyads showed the importance of the isoquinoline moiety in securing the photocatalytic activity.
Original languageEnglish
Pages (from-to)1982-1989
JournalPhotochemical and Photobiological Sciences
Volume18
Issue number8
Early online date17 Jun 2019
DOIs
Publication statusPublished - 2019

Scopus subject areas

  • Physical and Theoretical Chemistry

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