Abstract

The synthesis of conductive gold and copper-gold microstructures with high developed surface based on the method of laser-induced metal deposition from solution was developed. The topology and crystallization phase of these structures were observed by means of scanning electron microscopy and X-ray diffraction, respectively. The electrochemical properties of the synthesized materials were investigated using cyclic voltamperometry and amperometry. According to the obtained results, it was found out that copper-gold microstructures demonstrate a linear dependence of Faraday current vs. concentration from 0.025 to 5 mu M for n-glucose and from 0.025 to 10 mu M for hydrogen peroxide. In turn, gold deposit exhibits a linear dependence of Faraday current vs. concentration from 0.025 to 50 mu M for n-glucose and from 0.025 to 1 mu M for hydrogen peroxide. Moreover, the synthesized materials reveal low detection limits (0.025 mu M) with respect to the aforementioned analytes, which is quite promising for their potential application in design and fabrication of new non-enzymatic biosensors.

Original languageEnglish
Pages (from-to)201-207
Number of pages7
JournalTalanta
Volume167
DOIs
Publication statusPublished - 15 May 2017

Fingerprint

Gold
Copper
Lasers
Hydrogen Peroxide
Microstructure
Sensors
Gold deposits
Glucose
Crystallization
Electrochemical properties
Biosensors
Biosensing Techniques
Metals
Topology
X-Ray Diffraction
Electron Scanning Microscopy
Limit of Detection
Fabrication
X ray diffraction
Scanning electron microscopy

Cite this

@article{4c4f8b1c9e254e26a04e3a729a2e048c,
title = "Non-enzymatic sensors based on in situ laser-induced synthesis of copper gold and gold nano-sized microstructures",
abstract = "The synthesis of conductive gold and copper-gold microstructures with high developed surface based on the method of laser-induced metal deposition from solution was developed. The topology and crystallization phase of these structures were observed by means of scanning electron microscopy and X-ray diffraction, respectively. The electrochemical properties of the synthesized materials were investigated using cyclic voltamperometry and amperometry. According to the obtained results, it was found out that copper-gold microstructures demonstrate a linear dependence of Faraday current vs. concentration from 0.025 to 5 mu M for n-glucose and from 0.025 to 10 mu M for hydrogen peroxide. In turn, gold deposit exhibits a linear dependence of Faraday current vs. concentration from 0.025 to 50 mu M for n-glucose and from 0.025 to 1 mu M for hydrogen peroxide. Moreover, the synthesized materials reveal low detection limits (0.025 mu M) with respect to the aforementioned analytes, which is quite promising for their potential application in design and fabrication of new non-enzymatic biosensors.",
author = "Panov, {Maxim S.} and Vereshchagina, {Olga A.} and Ermakov, {Sergey S.} and Tumkin, {Ilya I.} and Khairullina, {Evgeniia M.} and Skripkin, {Mikhail Yu.} and Mereshchenko, {Andrey S.} and Ryazantsev, {Mikhail N.} and Kochemirovsky, {Vladimir A.}",
year = "2017",
month = "5",
day = "15",
doi = "10.1016/j.talanta.2017.01.089",
language = "Английский",
volume = "167",
pages = "201--207",
journal = "Talanta",
issn = "0039-9140",
publisher = "Elsevier",

}

TY - JOUR

T1 - Non-enzymatic sensors based on in situ laser-induced synthesis of copper gold and gold nano-sized microstructures

AU - Panov, Maxim S.

AU - Vereshchagina, Olga A.

AU - Ermakov, Sergey S.

AU - Tumkin, Ilya I.

AU - Khairullina, Evgeniia M.

AU - Skripkin, Mikhail Yu.

AU - Mereshchenko, Andrey S.

AU - Ryazantsev, Mikhail N.

AU - Kochemirovsky, Vladimir A.

PY - 2017/5/15

Y1 - 2017/5/15

N2 - The synthesis of conductive gold and copper-gold microstructures with high developed surface based on the method of laser-induced metal deposition from solution was developed. The topology and crystallization phase of these structures were observed by means of scanning electron microscopy and X-ray diffraction, respectively. The electrochemical properties of the synthesized materials were investigated using cyclic voltamperometry and amperometry. According to the obtained results, it was found out that copper-gold microstructures demonstrate a linear dependence of Faraday current vs. concentration from 0.025 to 5 mu M for n-glucose and from 0.025 to 10 mu M for hydrogen peroxide. In turn, gold deposit exhibits a linear dependence of Faraday current vs. concentration from 0.025 to 50 mu M for n-glucose and from 0.025 to 1 mu M for hydrogen peroxide. Moreover, the synthesized materials reveal low detection limits (0.025 mu M) with respect to the aforementioned analytes, which is quite promising for their potential application in design and fabrication of new non-enzymatic biosensors.

AB - The synthesis of conductive gold and copper-gold microstructures with high developed surface based on the method of laser-induced metal deposition from solution was developed. The topology and crystallization phase of these structures were observed by means of scanning electron microscopy and X-ray diffraction, respectively. The electrochemical properties of the synthesized materials were investigated using cyclic voltamperometry and amperometry. According to the obtained results, it was found out that copper-gold microstructures demonstrate a linear dependence of Faraday current vs. concentration from 0.025 to 5 mu M for n-glucose and from 0.025 to 10 mu M for hydrogen peroxide. In turn, gold deposit exhibits a linear dependence of Faraday current vs. concentration from 0.025 to 50 mu M for n-glucose and from 0.025 to 1 mu M for hydrogen peroxide. Moreover, the synthesized materials reveal low detection limits (0.025 mu M) with respect to the aforementioned analytes, which is quite promising for their potential application in design and fabrication of new non-enzymatic biosensors.

U2 - 10.1016/j.talanta.2017.01.089

DO - 10.1016/j.talanta.2017.01.089

M3 - статья

VL - 167

SP - 201

EP - 207

JO - Talanta

JF - Talanta

SN - 0039-9140

ER -