New Bis(salicylideneiminate) Nickel(II) Complexes with Carboxyethylene Linker Connecting Imine Groups and Their Electrochemical Polymerization

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Abstract

New nickel(II) bis(salicylideneiminate) complexes with carboxyethylene linker connecting imine groups were obtained. Polymer films based on these complexes were synthesized by electrochemical polymerization. When studying ionic transport in polymer films using cyclic voltammetry and microgravimetry, it was found that during oxidation, polymers pass into a self-doped state, in which a positive charge on the polymer chain is compensated by a negative charge of the carboxyl group, and a cation, forming an ionic pair with this group in neutral polymer form, leaves the film.

Original languageEnglish
Pages (from-to)852-855
Number of pages4
JournalRussian Journal of General Chemistry
Volume89
Issue number4
DOIs
Publication statusPublished - 1 Apr 2019

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Scopus subject areas

  • Chemistry(all)

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