Molecular, conformational, and optical characteristics of poly(cetylammonium-2-acrylamido-2-methylpropanesulfonate) obtained by micellar polymerization

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Abstract

The present work is focused on the detailed studies of molecular, conformational and optical properties of poly(cetylammonium-2-acrylamido-2-methylpropanesulfonate) (CA-PAMPS) obtained by polymerization of a new surface active monomer (cetylammonium-2-acrylamido-2-methylpropanesulfonate), CA-AMPS, in micellar solutions (where the choice of polymerization medium has an influence on micelle formation and molecular mass of the synthesized polymer). The Mark–Kuhn–Houwink equations for CA-PAMPS were obtained; equilibrium rigidity and hydrodynamic diameter of CA-PAMPS were determined, optical anisotropy of monomer unit was calculated. Molecular properties of CA-PAMPS were compared with those of previously studied poly(dodecylammonium-2-acrylamido-2-methylpropanesulfonate) (DDA-PAMPS); the latter polymer is similar to CA-PAMPS in structure, but possesses shorter side chains. The influence of formation of CA-AMPS monomer micelles on molecular mass of the obtained polymer was studied.
Original languageEnglish
Pages (from-to)251-263
JournalEuropean Polymer Journal
Volume75
DOIs
Publication statusPublished - 2016

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AMPS (satellite payload)
Polymers
polymerization
monomers
Monomers
molecular properties
Polymerization
Molecular mass
Micelles
micelles
polymers
Digital differential analyzers
Optical anisotropy
rigidity
Rigidity
Hydrodynamics
Optical properties
hydrodynamics
optical properties
anisotropy

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@article{302d280bd2aa4a69b750a9a2ea6ec41e,
title = "Molecular, conformational, and optical characteristics of poly(cetylammonium-2-acrylamido-2-methylpropanesulfonate) obtained by micellar polymerization",
abstract = "The present work is focused on the detailed studies of molecular, conformational and optical properties of poly(cetylammonium-2-acrylamido-2-methylpropanesulfonate) (CA-PAMPS) obtained by polymerization of a new surface active monomer (cetylammonium-2-acrylamido-2-methylpropanesulfonate), CA-AMPS, in micellar solutions (where the choice of polymerization medium has an influence on micelle formation and molecular mass of the synthesized polymer). The Mark–Kuhn–Houwink equations for CA-PAMPS were obtained; equilibrium rigidity and hydrodynamic diameter of CA-PAMPS were determined, optical anisotropy of monomer unit was calculated. Molecular properties of CA-PAMPS were compared with those of previously studied poly(dodecylammonium-2-acrylamido-2-methylpropanesulfonate) (DDA-PAMPS); the latter polymer is similar to CA-PAMPS in structure, but possesses shorter side chains. The influence of formation of CA-AMPS monomer micelles on molecular mass of the obtained polymer was studied.",
keywords = "Comb-like polymers, Macromolecule conformation, Optical anisotropy, ‘‘Surfmer”, Dynamic light scattering",
author = "Tsvetkov, {Nikolai V.} and Mikusheva, {Nina G.} and Lezov, {Alexey A.} and Gubarev, {Alexander S.} and Mikhailova, {Mariya E.} and Podseval’nikova, {Anna N.} and Akhmadeeva, {Liliya I.} and Lebedeva, {Elena V.} and Zorin, {Ivan M.} and Shcherbinina, {Tatiana M.} and Bilibin, {Alexander Yu.}",
year = "2016",
doi = "10.1016/j.eurpolymj.2015.12.022",
language = "English",
volume = "75",
pages = "251--263",
journal = "European Polymer Journal",
issn = "0014-3057",
publisher = "Elsevier",

}

TY - JOUR

T1 - Molecular, conformational, and optical characteristics of poly(cetylammonium-2-acrylamido-2-methylpropanesulfonate) obtained by micellar polymerization

AU - Tsvetkov, Nikolai V.

AU - Mikusheva, Nina G.

AU - Lezov, Alexey A.

AU - Gubarev, Alexander S.

AU - Mikhailova, Mariya E.

AU - Podseval’nikova, Anna N.

AU - Akhmadeeva, Liliya I.

AU - Lebedeva, Elena V.

AU - Zorin, Ivan M.

AU - Shcherbinina, Tatiana M.

AU - Bilibin, Alexander Yu.

PY - 2016

Y1 - 2016

N2 - The present work is focused on the detailed studies of molecular, conformational and optical properties of poly(cetylammonium-2-acrylamido-2-methylpropanesulfonate) (CA-PAMPS) obtained by polymerization of a new surface active monomer (cetylammonium-2-acrylamido-2-methylpropanesulfonate), CA-AMPS, in micellar solutions (where the choice of polymerization medium has an influence on micelle formation and molecular mass of the synthesized polymer). The Mark–Kuhn–Houwink equations for CA-PAMPS were obtained; equilibrium rigidity and hydrodynamic diameter of CA-PAMPS were determined, optical anisotropy of monomer unit was calculated. Molecular properties of CA-PAMPS were compared with those of previously studied poly(dodecylammonium-2-acrylamido-2-methylpropanesulfonate) (DDA-PAMPS); the latter polymer is similar to CA-PAMPS in structure, but possesses shorter side chains. The influence of formation of CA-AMPS monomer micelles on molecular mass of the obtained polymer was studied.

AB - The present work is focused on the detailed studies of molecular, conformational and optical properties of poly(cetylammonium-2-acrylamido-2-methylpropanesulfonate) (CA-PAMPS) obtained by polymerization of a new surface active monomer (cetylammonium-2-acrylamido-2-methylpropanesulfonate), CA-AMPS, in micellar solutions (where the choice of polymerization medium has an influence on micelle formation and molecular mass of the synthesized polymer). The Mark–Kuhn–Houwink equations for CA-PAMPS were obtained; equilibrium rigidity and hydrodynamic diameter of CA-PAMPS were determined, optical anisotropy of monomer unit was calculated. Molecular properties of CA-PAMPS were compared with those of previously studied poly(dodecylammonium-2-acrylamido-2-methylpropanesulfonate) (DDA-PAMPS); the latter polymer is similar to CA-PAMPS in structure, but possesses shorter side chains. The influence of formation of CA-AMPS monomer micelles on molecular mass of the obtained polymer was studied.

KW - Comb-like polymers

KW - Macromolecule conformation

KW - Optical anisotropy

KW - ‘‘Surfmer”

KW - Dynamic light scattering

U2 - 10.1016/j.eurpolymj.2015.12.022

DO - 10.1016/j.eurpolymj.2015.12.022

M3 - Article

VL - 75

SP - 251

EP - 263

JO - European Polymer Journal

JF - European Polymer Journal

SN - 0014-3057

ER -