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Mixed Uranyl Sulfate-Selenates: Evolution of Structural Topology and Complexity vs Chemical Composition. / Gurzhiy, Vladislav V.; Tyumentseva, Olga S.; Krivovichev, Sergey V.; Krivovichev, Vladimir G.; Tananaev, Ivan G.

In: Crystal Growth and Design, Vol. 16, No. 8, 23.06.2016, p. 4482-4492.

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@article{661ff23ae771441a8eeaf51ae73951b7,
title = "Mixed Uranyl Sulfate-Selenates: Evolution of Structural Topology and Complexity vs Chemical Composition",
abstract = "{\textcopyright} 2016 American Chemical Society.Phase formation in the aqueous system of uranyl nitrate, potassium hydroxide, and variable amounts of sulfuric and selenic acids has been investigated. Four different types of crystalline phases with variable S and Se contents were isolated and characterized using single-crystal X-ray diffraction (XRD) and IR spectroscopy. Topological analysis and information-based complexity calculations demonstrated the following: (a) the absence of a continuous solid solution in the system, (b) the absence of isotypic sulfate and selenate phases, and (c) the discovery of two layered topologies unprecedented among inorganic oxysalts.",
author = "Gurzhiy, {Vladislav V.} and Tyumentseva, {Olga S.} and Krivovichev, {Sergey V.} and Krivovichev, {Vladimir G.} and Tananaev, {Ivan G.}",
year = "2016",
month = jun,
day = "23",
doi = "10.1021/acs.cgd.6b00611",
language = "English",
volume = "16",
pages = "4482--4492",
journal = "Crystal Growth and Design",
issn = "1528-7483",
publisher = "American Chemical Society",
number = "8",

}

RIS

TY - JOUR

T1 - Mixed Uranyl Sulfate-Selenates: Evolution of Structural Topology and Complexity vs Chemical Composition

AU - Gurzhiy, Vladislav V.

AU - Tyumentseva, Olga S.

AU - Krivovichev, Sergey V.

AU - Krivovichev, Vladimir G.

AU - Tananaev, Ivan G.

PY - 2016/6/23

Y1 - 2016/6/23

N2 - © 2016 American Chemical Society.Phase formation in the aqueous system of uranyl nitrate, potassium hydroxide, and variable amounts of sulfuric and selenic acids has been investigated. Four different types of crystalline phases with variable S and Se contents were isolated and characterized using single-crystal X-ray diffraction (XRD) and IR spectroscopy. Topological analysis and information-based complexity calculations demonstrated the following: (a) the absence of a continuous solid solution in the system, (b) the absence of isotypic sulfate and selenate phases, and (c) the discovery of two layered topologies unprecedented among inorganic oxysalts.

AB - © 2016 American Chemical Society.Phase formation in the aqueous system of uranyl nitrate, potassium hydroxide, and variable amounts of sulfuric and selenic acids has been investigated. Four different types of crystalline phases with variable S and Se contents were isolated and characterized using single-crystal X-ray diffraction (XRD) and IR spectroscopy. Topological analysis and information-based complexity calculations demonstrated the following: (a) the absence of a continuous solid solution in the system, (b) the absence of isotypic sulfate and selenate phases, and (c) the discovery of two layered topologies unprecedented among inorganic oxysalts.

U2 - 10.1021/acs.cgd.6b00611

DO - 10.1021/acs.cgd.6b00611

M3 - Article

VL - 16

SP - 4482

EP - 4492

JO - Crystal Growth and Design

JF - Crystal Growth and Design

SN - 1528-7483

IS - 8

ER -

ID: 7927939