Magnesium acetate – an effective electrophilic activator of the carbonyl group in transesterification of dialkylaziridine dicarboxylates

Angelina V. Kazakova, Dmitriy V. Androsov, Alexander S. Konev, Alexander F. Khlebnikov

Research outputpeer-review

Abstract

[Figure not available: see fulltext.] A method for transesterification of the ester groups in dialkylaziridine dicarboxylates by electrophilic activation of the carbonyl group in the presence of magnesium acetate with the preservation of the aziridine ring was developed and the use of modified aziridine dicarboxylates in the synthesis of sterically hindered derivatives of fullerenes C60, 2',5'-disubstituted fulleropyrrolidines, was demonstrated.

Original languageEnglish
Pages (from-to)875-880
Number of pages6
JournalChemistry of Heterocyclic Compounds
Volume56
Issue number7
DOIs
Publication statusPublished - 21 Aug 2020

Scopus subject areas

  • Organic Chemistry
  • Chemistry(all)

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