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DOI

Two new layered barium perrhenate halides, BaX(ReO4) (X = Cl and Br), were prepared and their structures were refined from single-crystal and powder data, respectively. Both compounds are isostructural to the previously reported BaCl(MnO4), exhibiting a matlockite (PbFCl)-derived motif. The structure of previously reported PbBr(ReO4) was also refined, in order to obtain a complete data set; it is similar to PbCl(ReO4). The structures of Ba and Pb compounds correspond to the centro- and non-centrosymmetric versions (pseudo-polymorphs) of the same motif corresponding to the alternation of [M2X2]2+ litharge-derived slabs and double sheets of perrhenate anions. Strong relationships exist to the structures of LnX(TO4) (X = Cl, Br; T = Mo, W) which are monoclinically distorted versions of the orthorhombic permanganates and perrhenates. Crystal chemistry and further perspectives of the compounds with litharge slabs constructed of Cl, Br, and I-centered tetrahedra are discussed.

Original languageEnglish
Article number106576
Number of pages6
JournalSolid State Sciences
Volume114
DOIs
StatePublished - 1 Apr 2021

    Research areas

  • Crystal structure, Halides, Litharge, Matlockite derivatives, Perrhenates, SULFATES, CE, PR, LN, CRYSTAL-STRUCTURE, LA, BACL(CLO4), CHEMISTRY

    Scopus subject areas

  • Condensed Matter Physics
  • Chemistry(all)
  • Materials Science(all)

ID: 76240961