Isocyanide metal complexes in catalysis

Kamran T. Mahmudov, Vadim Yu Kukushkin, Atash V. Gurbanov, Mikhail A. Kinzhalov, Vadim P. Boyarskiy, M. Fátima C.Guedes da Silva, Armando J.L. Pombeiro

Research output: Contribution to journalReview articleResearchpeer-review

3 Citations (Scopus)

Abstract

The catalytic applications of isocyanide metal systems (from early to late transition metals) for organic transformations were systematically reviewed, and the studied transformations are also classified by type regardless of the metal center. A broad range of catalytic reactions of organic substrates has been developed including reactions of alkenes and alkynes, functionalization of E–H and E–E to multiple bonds, alkyl- and aryl-halides activation, nucleophilic addition, electron transfer catalysis, and photochemical reactions. This report gives a general overview of reaction routes, mechanisms, and driving forces and highlights the potential of isocyanide metal species, drawing attention to emerging putative targets.

Original languageEnglish
Pages (from-to)65-89
Number of pages25
JournalCoordination Chemistry Reviews
Volume384
DOIs
StatePublished - 1 Apr 2019

Keywords

  • Homogeneous and heterogeneous catalysis
  • Isocyanide metal complexes
  • Metal-catalyzed and metal-mediated reactions
  • Organic transformations
  • COORDINATION CHEMISTRY
  • COPPER-ISONITRILE COMPLEX
  • PALLADIUM COMPLEXES
  • SYNTHETIC REACTIONS
  • TRANSFER HYDROGENATION
  • CYCLIC-COMPOUNDS
  • RADICAL-ADDITION
  • TERT-ALKYL ISOCYANIDE
  • STEREOSELECTIVE-SYNTHESIS
  • INTRAMOLECULAR BIS-SILYLATION

Scopus subject areas

  • Materials Chemistry
  • Inorganic Chemistry
  • Physical and Theoretical Chemistry

Cite this

Mahmudov, Kamran T. ; Kukushkin, Vadim Yu ; Gurbanov, Atash V. ; Kinzhalov, Mikhail A. ; Boyarskiy, Vadim P. ; da Silva, M. Fátima C.Guedes ; Pombeiro, Armando J.L. / Isocyanide metal complexes in catalysis. In: Coordination Chemistry Reviews. 2019 ; Vol. 384. pp. 65-89.
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Isocyanide metal complexes in catalysis. / Mahmudov, Kamran T.; Kukushkin, Vadim Yu; Gurbanov, Atash V.; Kinzhalov, Mikhail A.; Boyarskiy, Vadim P.; da Silva, M. Fátima C.Guedes; Pombeiro, Armando J.L.

In: Coordination Chemistry Reviews, Vol. 384, 01.04.2019, p. 65-89.

Research output: Contribution to journalReview articleResearchpeer-review

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AU - Gurbanov, Atash V.

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