Intercalation of Methylamine into the Protonated Forms of Layered Perovskite-Like Oxides HLnTiO4 (Ln = La and Nd)

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2 Citations (Scopus)

Abstract

New hybrid organic-inorganic derivatives HLnTiO4 · CH3NH2 (Ln = La and Nd) are obtained via the intercalation of methylamine into the interlayer space of protonated layered perovskite-like titanates HLnTiO4. The existence of three stable methylamine derivatives, namely, α-, β-, and γ-forms, is found for each of the titanates. The thermal stability of the obtained intercalation products is studied and their structural parameters are determined.

Original languageEnglish
Pages (from-to)428-432
Number of pages5
JournalGlass Physics and Chemistry
Volume44
Issue number5
DOIs
Publication statusPublished - 1 Sep 2018

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titanates
Intercalation
intercalation
Perovskite
Oxides
Derivatives
oxides
interlayers
Thermodynamic stability
thermal stability
products
perovskite
methylamine

Scopus subject areas

  • Ceramics and Composites
  • Condensed Matter Physics
  • Materials Chemistry

Cite this

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title = "Intercalation of Methylamine into the Protonated Forms of Layered Perovskite-Like Oxides HLnTiO4 (Ln = La and Nd)",
abstract = "New hybrid organic-inorganic derivatives HLnTiO4 · CH3NH2 (Ln = La and Nd) are obtained via the intercalation of methylamine into the interlayer space of protonated layered perovskite-like titanates HLnTiO4. The existence of three stable methylamine derivatives, namely, α-, β-, and γ-forms, is found for each of the titanates. The thermal stability of the obtained intercalation products is studied and their structural parameters are determined.",
keywords = "hydrothermal microwave synthesis, intercalation, layered titanate, methylamine, organic-inorganic compounds",
author = "Silyukov, {O. I.} and Kurnosenko, {S. A.} and Zvereva, {I. A.}",
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T1 - Intercalation of Methylamine into the Protonated Forms of Layered Perovskite-Like Oxides HLnTiO4 (Ln = La and Nd)

AU - Silyukov, O. I.

AU - Kurnosenko, S. A.

AU - Zvereva, I. A.

PY - 2018/9/1

Y1 - 2018/9/1

N2 - New hybrid organic-inorganic derivatives HLnTiO4 · CH3NH2 (Ln = La and Nd) are obtained via the intercalation of methylamine into the interlayer space of protonated layered perovskite-like titanates HLnTiO4. The existence of three stable methylamine derivatives, namely, α-, β-, and γ-forms, is found for each of the titanates. The thermal stability of the obtained intercalation products is studied and their structural parameters are determined.

AB - New hybrid organic-inorganic derivatives HLnTiO4 · CH3NH2 (Ln = La and Nd) are obtained via the intercalation of methylamine into the interlayer space of protonated layered perovskite-like titanates HLnTiO4. The existence of three stable methylamine derivatives, namely, α-, β-, and γ-forms, is found for each of the titanates. The thermal stability of the obtained intercalation products is studied and their structural parameters are determined.

KW - hydrothermal microwave synthesis

KW - intercalation

KW - layered titanate

KW - methylamine

KW - organic-inorganic compounds

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U2 - 10.1134/S1087659618050176

DO - 10.1134/S1087659618050176

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SP - 428

EP - 432

JO - Glass Physics and Chemistry

JF - Glass Physics and Chemistry

SN - 1087-6596

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