Functionalized Polynorbornenes with Oligoether Units and Luminophoric Iridium(III) Complexes in Side Chains. Synthesis, Photophysical, and Biological Properties

E. O. Platonova, A. V. Rozhkov, S. A. Lermontova, L. G. Klapshina, A. N. Konev, L. N. Bochkarev, G. A. Abakumov

Research output

1 Citation (Scopus)

Abstract

Copolymers with oligoether units and luminophoric iridium(III) complexes in the side chains have been synthesized via metathesis polymerization. The copolymers containing different luminophoric iridium(III) complexes have exhibited strong green, blue-green, or red photoluminescence. The copolymers are soluble in water, forming micelles with average size 14‒20 nm. The copolymer with red photoluminescence has low cytotoxicity with respect to epidermoid human carcinoma cells (line A431).

Original languageEnglish
Pages (from-to)731-735
Number of pages5
JournalRussian Journal of General Chemistry
Volume88
Issue number4
DOIs
Publication statusPublished - 1 Apr 2018

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Iridium
Copolymers
Photoluminescence
Micelles
Cytotoxicity
Polymerization
Cells
Water

Scopus subject areas

  • Chemistry(all)

Cite this

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title = "Functionalized Polynorbornenes with Oligoether Units and Luminophoric Iridium(III) Complexes in Side Chains. Synthesis, Photophysical, and Biological Properties",
abstract = "Copolymers with oligoether units and luminophoric iridium(III) complexes in the side chains have been synthesized via metathesis polymerization. The copolymers containing different luminophoric iridium(III) complexes have exhibited strong green, blue-green, or red photoluminescence. The copolymers are soluble in water, forming micelles with average size 14‒20 nm. The copolymer with red photoluminescence has low cytotoxicity with respect to epidermoid human carcinoma cells (line A431).",
keywords = "functionalized polynorbornenes, iridium-containing polymers, luminophoric iridium(III) complex, metathesis polymerization",
author = "Platonova, {E. O.} and Rozhkov, {A. V.} and Lermontova, {S. A.} and Klapshina, {L. G.} and Konev, {A. N.} and Bochkarev, {L. N.} and Abakumov, {G. A.}",
year = "2018",
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journal = "Russian Journal of General Chemistry",
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Functionalized Polynorbornenes with Oligoether Units and Luminophoric Iridium(III) Complexes in Side Chains. Synthesis, Photophysical, and Biological Properties. / Platonova, E. O.; Rozhkov, A. V.; Lermontova, S. A.; Klapshina, L. G.; Konev, A. N.; Bochkarev, L. N.; Abakumov, G. A.

In: Russian Journal of General Chemistry, Vol. 88, No. 4, 01.04.2018, p. 731-735.

Research output

TY - JOUR

T1 - Functionalized Polynorbornenes with Oligoether Units and Luminophoric Iridium(III) Complexes in Side Chains. Synthesis, Photophysical, and Biological Properties

AU - Platonova, E. O.

AU - Rozhkov, A. V.

AU - Lermontova, S. A.

AU - Klapshina, L. G.

AU - Konev, A. N.

AU - Bochkarev, L. N.

AU - Abakumov, G. A.

PY - 2018/4/1

Y1 - 2018/4/1

N2 - Copolymers with oligoether units and luminophoric iridium(III) complexes in the side chains have been synthesized via metathesis polymerization. The copolymers containing different luminophoric iridium(III) complexes have exhibited strong green, blue-green, or red photoluminescence. The copolymers are soluble in water, forming micelles with average size 14‒20 nm. The copolymer with red photoluminescence has low cytotoxicity with respect to epidermoid human carcinoma cells (line A431).

AB - Copolymers with oligoether units and luminophoric iridium(III) complexes in the side chains have been synthesized via metathesis polymerization. The copolymers containing different luminophoric iridium(III) complexes have exhibited strong green, blue-green, or red photoluminescence. The copolymers are soluble in water, forming micelles with average size 14‒20 nm. The copolymer with red photoluminescence has low cytotoxicity with respect to epidermoid human carcinoma cells (line A431).

KW - functionalized polynorbornenes

KW - iridium-containing polymers

KW - luminophoric iridium(III) complex

KW - metathesis polymerization

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U2 - 10.1134/S1070363218040175

DO - 10.1134/S1070363218040175

M3 - Article

AN - SCOPUS:85048301609

VL - 88

SP - 731

EP - 735

JO - Russian Journal of General Chemistry

JF - Russian Journal of General Chemistry

SN - 1070-3632

IS - 4

ER -