Formation of vanadium-containing nanostructures on the surface of protonated forms of layered perovskite-like titanates K2La2Ti3O10 and NaLaTiO4

Oleg I. Silyukov, Liliia D. Kulish, Dariya V. Trofimova, Alena A. Burovikhina, Mikhail V. Chislov, Ivan A. Rodionov, Yuri M. Zhukov, Irina A. Zvereva

Research output

3 Citations (Scopus)

Abstract

Reactions of layered perovskite-like oxides K2La2Ti3O10, NaLaTiO4 and corresponding protonated oxides H2La2Ti3O10, HLaTiO4 with vanadyl sulfate aqueous solution have been studied. It was revealed that the exchange reaction of interlayer alkali cations in K2La2Ti3O10 and NaLaTiO4 by with vanadyl cations, which was reported in the literature previously, does not proceed. The formation of the corresponding protonated forms and vanadium-containing particles is found to occur instead. In the case of protonated forms H2La2Ti3O10, HLaTiO4 vanadium-containing nanostructures are formed on the surface.

Original languageEnglish
Pages (from-to)28-34
Number of pages7
JournalJournal of Solid State Chemistry
Volume259
DOIs
Publication statusPublished - 1 Mar 2018

Fingerprint

titanates
Vanadium
Perovskite
Oxides
vanadium
Cations
Nanostructures
Positive ions
cations
Vanadates
oxides
Alkalies
sulfates
interlayers
alkalies
Ion exchange
aqueous solutions
perovskite
vanadyl sulfate
Sulfates

Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Ceramics and Composites
  • Condensed Matter Physics
  • Physical and Theoretical Chemistry
  • Inorganic Chemistry
  • Materials Chemistry

Cite this

@article{c17647a747f94cfea7abce727241af33,
title = "Formation of vanadium-containing nanostructures on the surface of protonated forms of layered perovskite-like titanates K2La2Ti3O10 and NaLaTiO4",
abstract = "Reactions of layered perovskite-like oxides K2La2Ti3O10, NaLaTiO4 and corresponding protonated oxides H2La2Ti3O10, HLaTiO4 with vanadyl sulfate aqueous solution have been studied. It was revealed that the exchange reaction of interlayer alkali cations in K2La2Ti3O10 and NaLaTiO4 by with vanadyl cations, which was reported in the literature previously, does not proceed. The formation of the corresponding protonated forms and vanadium-containing particles is found to occur instead. In the case of protonated forms H2La2Ti3O10, HLaTiO4 vanadium-containing nanostructures are formed on the surface.",
keywords = "Layered oxides, Nanostructure, Perovskite-like oxides, Vanadium",
author = "Silyukov, {Oleg I.} and Kulish, {Liliia D.} and Trofimova, {Dariya V.} and Burovikhina, {Alena A.} and Chislov, {Mikhail V.} and Rodionov, {Ivan A.} and Zhukov, {Yuri M.} and Zvereva, {Irina A.}",
year = "2018",
month = "3",
day = "1",
doi = "10.1016/j.jssc.2017.12.032",
language = "English",
volume = "259",
pages = "28--34",
journal = "Journal of Solid State Chemistry",
issn = "0022-4596",
publisher = "Elsevier",

}

Formation of vanadium-containing nanostructures on the surface of protonated forms of layered perovskite-like titanates K2La2Ti3O10 and NaLaTiO4. / Silyukov, Oleg I.; Kulish, Liliia D.; Trofimova, Dariya V.; Burovikhina, Alena A.; Chislov, Mikhail V.; Rodionov, Ivan A.; Zhukov, Yuri M.; Zvereva, Irina A.

In: Journal of Solid State Chemistry, Vol. 259, 01.03.2018, p. 28-34.

Research output

TY - JOUR

T1 - Formation of vanadium-containing nanostructures on the surface of protonated forms of layered perovskite-like titanates K2La2Ti3O10 and NaLaTiO4

AU - Silyukov, Oleg I.

AU - Kulish, Liliia D.

AU - Trofimova, Dariya V.

AU - Burovikhina, Alena A.

AU - Chislov, Mikhail V.

AU - Rodionov, Ivan A.

AU - Zhukov, Yuri M.

AU - Zvereva, Irina A.

PY - 2018/3/1

Y1 - 2018/3/1

N2 - Reactions of layered perovskite-like oxides K2La2Ti3O10, NaLaTiO4 and corresponding protonated oxides H2La2Ti3O10, HLaTiO4 with vanadyl sulfate aqueous solution have been studied. It was revealed that the exchange reaction of interlayer alkali cations in K2La2Ti3O10 and NaLaTiO4 by with vanadyl cations, which was reported in the literature previously, does not proceed. The formation of the corresponding protonated forms and vanadium-containing particles is found to occur instead. In the case of protonated forms H2La2Ti3O10, HLaTiO4 vanadium-containing nanostructures are formed on the surface.

AB - Reactions of layered perovskite-like oxides K2La2Ti3O10, NaLaTiO4 and corresponding protonated oxides H2La2Ti3O10, HLaTiO4 with vanadyl sulfate aqueous solution have been studied. It was revealed that the exchange reaction of interlayer alkali cations in K2La2Ti3O10 and NaLaTiO4 by with vanadyl cations, which was reported in the literature previously, does not proceed. The formation of the corresponding protonated forms and vanadium-containing particles is found to occur instead. In the case of protonated forms H2La2Ti3O10, HLaTiO4 vanadium-containing nanostructures are formed on the surface.

KW - Layered oxides

KW - Nanostructure

KW - Perovskite-like oxides

KW - Vanadium

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U2 - 10.1016/j.jssc.2017.12.032

DO - 10.1016/j.jssc.2017.12.032

M3 - Article

AN - SCOPUS:85039991211

VL - 259

SP - 28

EP - 34

JO - Journal of Solid State Chemistry

JF - Journal of Solid State Chemistry

SN - 0022-4596

ER -