Research output: Contribution to journal › Article › peer-review
Fluorination of polystyrene by elemental fluorine in liquid media. / Blinov, Ilya A.; Belov, Nikolay A.; Suvorov, Alexander V.; Chirkov, Sergey V.; Kostina, Yulia V.; Mazur, Anton S.; Kambur, Marina P.; Belochvostov, Vasilii M.; Alentiev, Alexander Yu; Vozniuk, Olesia N.; Yampolskii, Yurii P.
In: Journal of Fluorine Chemistry, Vol. 246, 109777, 01.06.2021.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Fluorination of polystyrene by elemental fluorine in liquid media
AU - Blinov, Ilya A.
AU - Belov, Nikolay A.
AU - Suvorov, Alexander V.
AU - Chirkov, Sergey V.
AU - Kostina, Yulia V.
AU - Mazur, Anton S.
AU - Kambur, Marina P.
AU - Belochvostov, Vasilii M.
AU - Alentiev, Alexander Yu
AU - Vozniuk, Olesia N.
AU - Yampolskii, Yurii P.
N1 - Publisher Copyright: © 2021 Elsevier B.V.
PY - 2021/6/1
Y1 - 2021/6/1
N2 - Fluorinated polystyrene has a number of attractive properties, but its synthesis is rather complicated. In this regard, it seems attractive to obtain polyfluorstyrene by direct fluorination of polystyrene under “mild” conditions – in the form of a suspension in a perfluorinated liquid. The fluorinated polymer was characterized by IR and 19F and 13C solid-state NMR spectroscopy. It was shown that non-destructive hydrogen-substituting fluorination prevails under these “mild” conditions; fluorination occurs into the benzene ring and into the main carbon chain.
AB - Fluorinated polystyrene has a number of attractive properties, but its synthesis is rather complicated. In this regard, it seems attractive to obtain polyfluorstyrene by direct fluorination of polystyrene under “mild” conditions – in the form of a suspension in a perfluorinated liquid. The fluorinated polymer was characterized by IR and 19F and 13C solid-state NMR spectroscopy. It was shown that non-destructive hydrogen-substituting fluorination prevails under these “mild” conditions; fluorination occurs into the benzene ring and into the main carbon chain.
KW - Direct fluorination
KW - Fluorine
KW - Gas-liquid reactor
KW - Perfluorodecalin
KW - Polystyrene
KW - Solid-state NMR
KW - POLYMERS
KW - TRANSPORT
KW - SURFACE-LAYER
UR - http://www.scopus.com/inward/record.url?scp=85103963613&partnerID=8YFLogxK
UR - https://www.mendeley.com/catalogue/490a7aab-3ae9-3d52-b64b-6fcb616f5fb9/
U2 - 10.1016/j.jfluchem.2021.109777
DO - 10.1016/j.jfluchem.2021.109777
M3 - Article
AN - SCOPUS:85103963613
VL - 246
JO - Journal of Fluorine Chemistry
JF - Journal of Fluorine Chemistry
SN - 0022-1139
M1 - 109777
ER -
ID: 86375057