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Fluorination of polystyrene by elemental fluorine in liquid media. / Blinov, Ilya A.; Belov, Nikolay A.; Suvorov, Alexander V.; Chirkov, Sergey V.; Kostina, Yulia V.; Mazur, Anton S.; Kambur, Marina P.; Belochvostov, Vasilii M.; Alentiev, Alexander Yu; Vozniuk, Olesia N.; Yampolskii, Yurii P.

In: Journal of Fluorine Chemistry, Vol. 246, 109777, 01.06.2021.

Research output: Contribution to journalArticlepeer-review

Harvard

Blinov, IA, Belov, NA, Suvorov, AV, Chirkov, SV, Kostina, YV, Mazur, AS, Kambur, MP, Belochvostov, VM, Alentiev, AY, Vozniuk, ON & Yampolskii, YP 2021, 'Fluorination of polystyrene by elemental fluorine in liquid media', Journal of Fluorine Chemistry, vol. 246, 109777. https://doi.org/10.1016/j.jfluchem.2021.109777

APA

Blinov, I. A., Belov, N. A., Suvorov, A. V., Chirkov, S. V., Kostina, Y. V., Mazur, A. S., Kambur, M. P., Belochvostov, V. M., Alentiev, A. Y., Vozniuk, O. N., & Yampolskii, Y. P. (2021). Fluorination of polystyrene by elemental fluorine in liquid media. Journal of Fluorine Chemistry, 246, [109777]. https://doi.org/10.1016/j.jfluchem.2021.109777

Vancouver

Blinov IA, Belov NA, Suvorov AV, Chirkov SV, Kostina YV, Mazur AS et al. Fluorination of polystyrene by elemental fluorine in liquid media. Journal of Fluorine Chemistry. 2021 Jun 1;246. 109777. https://doi.org/10.1016/j.jfluchem.2021.109777

Author

Blinov, Ilya A. ; Belov, Nikolay A. ; Suvorov, Alexander V. ; Chirkov, Sergey V. ; Kostina, Yulia V. ; Mazur, Anton S. ; Kambur, Marina P. ; Belochvostov, Vasilii M. ; Alentiev, Alexander Yu ; Vozniuk, Olesia N. ; Yampolskii, Yurii P. / Fluorination of polystyrene by elemental fluorine in liquid media. In: Journal of Fluorine Chemistry. 2021 ; Vol. 246.

BibTeX

@article{ebc6407734db41d79d2e2107db447a4f,
title = "Fluorination of polystyrene by elemental fluorine in liquid media",
abstract = "Fluorinated polystyrene has a number of attractive properties, but its synthesis is rather complicated. In this regard, it seems attractive to obtain polyfluorstyrene by direct fluorination of polystyrene under “mild” conditions – in the form of a suspension in a perfluorinated liquid. The fluorinated polymer was characterized by IR and 19F and 13C solid-state NMR spectroscopy. It was shown that non-destructive hydrogen-substituting fluorination prevails under these “mild” conditions; fluorination occurs into the benzene ring and into the main carbon chain.",
keywords = "Direct fluorination, Fluorine, Gas-liquid reactor, Perfluorodecalin, Polystyrene, Solid-state NMR, POLYMERS, TRANSPORT, SURFACE-LAYER",
author = "Blinov, {Ilya A.} and Belov, {Nikolay A.} and Suvorov, {Alexander V.} and Chirkov, {Sergey V.} and Kostina, {Yulia V.} and Mazur, {Anton S.} and Kambur, {Marina P.} and Belochvostov, {Vasilii M.} and Alentiev, {Alexander Yu} and Vozniuk, {Olesia N.} and Yampolskii, {Yurii P.}",
note = "Publisher Copyright: {\textcopyright} 2021 Elsevier B.V.",
year = "2021",
month = jun,
day = "1",
doi = "10.1016/j.jfluchem.2021.109777",
language = "English",
volume = "246",
journal = "Journal of Fluorine Chemistry",
issn = "0022-1139",
publisher = "Elsevier",

}

RIS

TY - JOUR

T1 - Fluorination of polystyrene by elemental fluorine in liquid media

AU - Blinov, Ilya A.

AU - Belov, Nikolay A.

AU - Suvorov, Alexander V.

AU - Chirkov, Sergey V.

AU - Kostina, Yulia V.

AU - Mazur, Anton S.

AU - Kambur, Marina P.

AU - Belochvostov, Vasilii M.

AU - Alentiev, Alexander Yu

AU - Vozniuk, Olesia N.

AU - Yampolskii, Yurii P.

N1 - Publisher Copyright: © 2021 Elsevier B.V.

PY - 2021/6/1

Y1 - 2021/6/1

N2 - Fluorinated polystyrene has a number of attractive properties, but its synthesis is rather complicated. In this regard, it seems attractive to obtain polyfluorstyrene by direct fluorination of polystyrene under “mild” conditions – in the form of a suspension in a perfluorinated liquid. The fluorinated polymer was characterized by IR and 19F and 13C solid-state NMR spectroscopy. It was shown that non-destructive hydrogen-substituting fluorination prevails under these “mild” conditions; fluorination occurs into the benzene ring and into the main carbon chain.

AB - Fluorinated polystyrene has a number of attractive properties, but its synthesis is rather complicated. In this regard, it seems attractive to obtain polyfluorstyrene by direct fluorination of polystyrene under “mild” conditions – in the form of a suspension in a perfluorinated liquid. The fluorinated polymer was characterized by IR and 19F and 13C solid-state NMR spectroscopy. It was shown that non-destructive hydrogen-substituting fluorination prevails under these “mild” conditions; fluorination occurs into the benzene ring and into the main carbon chain.

KW - Direct fluorination

KW - Fluorine

KW - Gas-liquid reactor

KW - Perfluorodecalin

KW - Polystyrene

KW - Solid-state NMR

KW - POLYMERS

KW - TRANSPORT

KW - SURFACE-LAYER

UR - http://www.scopus.com/inward/record.url?scp=85103963613&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/490a7aab-3ae9-3d52-b64b-6fcb616f5fb9/

U2 - 10.1016/j.jfluchem.2021.109777

DO - 10.1016/j.jfluchem.2021.109777

M3 - Article

AN - SCOPUS:85103963613

VL - 246

JO - Journal of Fluorine Chemistry

JF - Journal of Fluorine Chemistry

SN - 0022-1139

M1 - 109777

ER -

ID: 86375057