First example of a click-reaction on the aminate copper complexes: effect of reaction parameters

Igor V. Esarev, Vladislav V. Gurzhiy, Artem A. Selyutin, Anastasia V. Laptenkova, Andrey I. Poddel'sky, Nicolay L. Medvedskiy, Alexander I. Ponyaev, Rostislav E. Trifonov, Alexey V. Eremin

Research output

Abstract

The hydrothermal reaction of NaN3 with Cu(Phen)Cl2 in acetonitrile solutions results in the formation of two complexes: new d9 mononuclear cis-[CuII(Phen)2(mtz)2]·H2O and d10 coordination polymer catena-[CuI(Phen)(μ-CN)]n (mtz is 5-methyltetrazolate anion and Phen is 1,10-phenanthroline). The process involves in situ formation of mtz ligand via cycloaddition of acetonitrile and azide (in the case of [CuII(Phen)2(mtz)2]) and cleavage of acetonitrile C–C bond (in the case of [CuI(Phen)(μ-CN)]n). Both complexes were fully characterized by a comprehensive set of methods, including the single crystal X-ray diffraction data.

Original languageEnglish
Pages (from-to)606-608
Number of pages3
JournalMendeleev Communications
Volume28
Issue number6
DOIs
Publication statusPublished - 1 Nov 2018

Fingerprint

Copper
Sodium Azide
Azides
Cycloaddition
Anions
Polymers
Single crystals
Ligands
X ray diffraction
acetonitrile
1,10-phenanthroline

Scopus subject areas

  • Chemistry(all)

Cite this

Esarev, Igor V. ; Gurzhiy, Vladislav V. ; Selyutin, Artem A. ; Laptenkova, Anastasia V. ; Poddel'sky, Andrey I. ; Medvedskiy, Nicolay L. ; Ponyaev, Alexander I. ; Trifonov, Rostislav E. ; Eremin, Alexey V. / First example of a click-reaction on the aminate copper complexes : effect of reaction parameters. In: Mendeleev Communications. 2018 ; Vol. 28, No. 6. pp. 606-608.
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abstract = "The hydrothermal reaction of NaN3 with Cu(Phen)Cl2 in acetonitrile solutions results in the formation of two complexes: new d9 mononuclear cis-[CuII(Phen)2(mtz)2]·H2O and d10 coordination polymer catena-[CuI(Phen)(μ-CN)]n (mtz is 5-methyltetrazolate anion and Phen is 1,10-phenanthroline). The process involves in situ formation of mtz ligand via cycloaddition of acetonitrile and azide (in the case of [CuII(Phen)2(mtz)2]) and cleavage of acetonitrile C–C bond (in the case of [CuI(Phen)(μ-CN)]n). Both complexes were fully characterized by a comprehensive set of methods, including the single crystal X-ray diffraction data.",
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First example of a click-reaction on the aminate copper complexes : effect of reaction parameters. / Esarev, Igor V.; Gurzhiy, Vladislav V.; Selyutin, Artem A.; Laptenkova, Anastasia V.; Poddel'sky, Andrey I.; Medvedskiy, Nicolay L.; Ponyaev, Alexander I.; Trifonov, Rostislav E.; Eremin, Alexey V.

In: Mendeleev Communications, Vol. 28, No. 6, 01.11.2018, p. 606-608.

Research output

TY - JOUR

T1 - First example of a click-reaction on the aminate copper complexes

T2 - effect of reaction parameters

AU - Esarev, Igor V.

AU - Gurzhiy, Vladislav V.

AU - Selyutin, Artem A.

AU - Laptenkova, Anastasia V.

AU - Poddel'sky, Andrey I.

AU - Medvedskiy, Nicolay L.

AU - Ponyaev, Alexander I.

AU - Trifonov, Rostislav E.

AU - Eremin, Alexey V.

PY - 2018/11/1

Y1 - 2018/11/1

N2 - The hydrothermal reaction of NaN3 with Cu(Phen)Cl2 in acetonitrile solutions results in the formation of two complexes: new d9 mononuclear cis-[CuII(Phen)2(mtz)2]·H2O and d10 coordination polymer catena-[CuI(Phen)(μ-CN)]n (mtz is 5-methyltetrazolate anion and Phen is 1,10-phenanthroline). The process involves in situ formation of mtz ligand via cycloaddition of acetonitrile and azide (in the case of [CuII(Phen)2(mtz)2]) and cleavage of acetonitrile C–C bond (in the case of [CuI(Phen)(μ-CN)]n). Both complexes were fully characterized by a comprehensive set of methods, including the single crystal X-ray diffraction data.

AB - The hydrothermal reaction of NaN3 with Cu(Phen)Cl2 in acetonitrile solutions results in the formation of two complexes: new d9 mononuclear cis-[CuII(Phen)2(mtz)2]·H2O and d10 coordination polymer catena-[CuI(Phen)(μ-CN)]n (mtz is 5-methyltetrazolate anion and Phen is 1,10-phenanthroline). The process involves in situ formation of mtz ligand via cycloaddition of acetonitrile and azide (in the case of [CuII(Phen)2(mtz)2]) and cleavage of acetonitrile C–C bond (in the case of [CuI(Phen)(μ-CN)]n). Both complexes were fully characterized by a comprehensive set of methods, including the single crystal X-ray diffraction data.

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