First example of a click-reaction on the aminate copper complexes: effect of reaction parameters

Igor V. Esarev, Vladislav V. Gurzhiy, Artem A. Selyutin, Anastasia V. Laptenkova, Andrey I. Poddel'sky, Nicolay L. Medvedskiy, Alexander I. Ponyaev, Rostislav E. Trifonov, Alexey V. Eremin

Research output: Contribution to journalArticlepeer-review

1 Scopus citations

Abstract

The hydrothermal reaction of NaN3 with Cu(Phen)Cl2 in acetonitrile solutions results in the formation of two complexes: new d9 mononuclear cis-[CuII(Phen)2(mtz)2]·H2O and d10 coordination polymer catena-[CuI(Phen)(μ-CN)]n (mtz is 5-methyltetrazolate anion and Phen is 1,10-phenanthroline). The process involves in situ formation of mtz ligand via cycloaddition of acetonitrile and azide (in the case of [CuII(Phen)2(mtz)2]) and cleavage of acetonitrile C–C bond (in the case of [CuI(Phen)(μ-CN)]n). Both complexes were fully characterized by a comprehensive set of methods, including the single crystal X-ray diffraction data.

Original languageEnglish
Pages (from-to)606-608
Number of pages3
JournalMendeleev Communications
Volume28
Issue number6
DOIs
StatePublished - 1 Nov 2018

Scopus subject areas

  • Chemistry(all)

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