Direct conversion of diazo compounds to fluoro derivatives

Standard

Direct conversion of diazo compounds to fluoro derivatives. / Burianova, Valeria ; Dar'in, Dmitry ; Krasavin, Mikhail.

In: Tetrahedron Letters, Vol. 61, No. 35, 152255, 27.08.2020.

Research output: Contribution to journal › Review article › peer-review

BibTeX

@article{e5efe86b3a7c4553bf5cb62808faf0c6,

title = "Direct conversion of diazo compounds to fluoro derivatives",

abstract = "As described for the first time in 1974 by Olah, diazo function can be directly converted to a combination of a fluorine atom with other substituents (such as hydrogen atom, another fluorine atom, other halogens, oxy or amino substituents or an aromatic ring). These reactions offer a direct entry into novel fluorinated scaffolds via metal-catalyzed or metal-free reactions. Some of these methods can be adopted to the stringent requirements of producing short-lived 18F tracers for positron emission tomography. The full range of literature (1974–2020) on the topic is reviewed in this digest.",

keywords = "Diazo compounds, Diflurination, Electrophilic fluorine sources, Fluorination, Halofluorination, Hydrofluorination, Metal carbene, PET tracers, ALPHA-DIAZOCARBONYL COMPOUNDS, FLUORINATION, AZIDE, KETONES, DICHLORINATION, AMINOFLUORINATION, DIAZOKETONES",

author = "Valeria Burianova and Dmitry Dar'in and Mikhail Krasavin",

year = "2020",

month = aug,

day = "27",

doi = "10.1016/j.tetlet.2020.152255",

language = "English",

volume = "61",

journal = "Tetrahedron Letters",

issn = "0040-4039",

publisher = "Elsevier",

number = "35",

}

RIS

TY - JOUR

T1 - Direct conversion of diazo compounds to fluoro derivatives

AU - Burianova, Valeria

AU - Dar'in, Dmitry

AU - Krasavin, Mikhail

PY - 2020/8/27

Y1 - 2020/8/27

N2 - As described for the first time in 1974 by Olah, diazo function can be directly converted to a combination of a fluorine atom with other substituents (such as hydrogen atom, another fluorine atom, other halogens, oxy or amino substituents or an aromatic ring). These reactions offer a direct entry into novel fluorinated scaffolds via metal-catalyzed or metal-free reactions. Some of these methods can be adopted to the stringent requirements of producing short-lived 18F tracers for positron emission tomography. The full range of literature (1974–2020) on the topic is reviewed in this digest.

AB - As described for the first time in 1974 by Olah, diazo function can be directly converted to a combination of a fluorine atom with other substituents (such as hydrogen atom, another fluorine atom, other halogens, oxy or amino substituents or an aromatic ring). These reactions offer a direct entry into novel fluorinated scaffolds via metal-catalyzed or metal-free reactions. Some of these methods can be adopted to the stringent requirements of producing short-lived 18F tracers for positron emission tomography. The full range of literature (1974–2020) on the topic is reviewed in this digest.

KW - Diazo compounds

KW - Diflurination

KW - Electrophilic fluorine sources

KW - Fluorination

KW - Halofluorination

KW - Hydrofluorination

KW - Metal carbene

KW - PET tracers

KW - ALPHA-DIAZOCARBONYL COMPOUNDS

KW - FLUORINATION

KW - AZIDE

KW - KETONES

KW - DICHLORINATION

KW - AMINOFLUORINATION

KW - DIAZOKETONES

UR - http://www.scopus.com/inward/record.url?scp=85089070248&partnerID=8YFLogxK

UR - https://www.mendeley.com/catalogue/8cc1d8a7-e227-36ff-9018-8e6f1d2fffb8/

U2 - 10.1016/j.tetlet.2020.152255

DO - 10.1016/j.tetlet.2020.152255

M3 - Review article

AN - SCOPUS:85089070248

VL - 61

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 35

M1 - 152255

ER -

ID: 61393557