Dialkyl diazomalonates in transition-metal-free, thermally promoted, diastereoselective wolff β-lactam synthesis

Judith Synofzik, Olga Bakulina, Dmitry Dar'in, Grigory Kantin, Mikhail Krasavin

Research output

1 Citation (Scopus)

Abstract

Metal-free, thermally promoted synthesis of 3-alkoxy-3-alkoxycarbonyl-2-azetidinones via the Wolff-Staudinger β-lactam synthesis using dialkyl diazomalonates is described. The reaction appears fairly general and delivers only one diastereomer.

Original languageEnglish
Pages (from-to)1273-1276
Number of pages4
JournalSynlett
Volume31
Issue number13
DOIs
Publication statusPublished - 12 Aug 2020

Scopus subject areas

  • Organic Chemistry

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