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Design of luminescent complexes with different Cu4I4 cores based on pyridyl phenoxarsines. / Galimova, Milyausha F.; Zueva, Ekaterina M.; Petrova, Maria M. ; Dobrynin, Alexey B.; Kolesnikov, Ilya E.; Musina, Elvira I.; Musin, Rustem R.; Karasik, Andrey A.; Sinyashin, Oleg G.

In: Dalton Transactions, Vol. 53, No. 3, 01.01.2024, p. 1087-1098.

Research output: Contribution to journal › Article › peer-review

Harvard

Galimova, MF, Zueva, EM, Petrova, MM, Dobrynin, AB, Kolesnikov, IE, Musina, EI, Musin, RR, Karasik, AA & Sinyashin, OG 2024, 'Design of luminescent complexes with different Cu4I4 cores based on pyridyl phenoxarsines', Dalton Transactions, vol. 53, no. 3, pp. 1087-1098. https://doi.org/10.1039/D3DT03273F, https://doi.org/10.1039/d3dt03273f

APA

Galimova, M. F., Zueva, E. M., Petrova, M. M., Dobrynin, A. B., Kolesnikov, I. E., Musina, E. I., Musin, R. R., Karasik, A. A., & Sinyashin, O. G. (2024). Design of luminescent complexes with different Cu4I4 cores based on pyridyl phenoxarsines. Dalton Transactions, 53(3), 1087-1098. https://doi.org/10.1039/D3DT03273F, https://doi.org/10.1039/d3dt03273f

Vancouver

Galimova MF, Zueva EM, Petrova MM, Dobrynin AB, Kolesnikov IE, Musina EI et al. Design of luminescent complexes with different Cu4I4 cores based on pyridyl phenoxarsines. Dalton Transactions. 2024 Jan 1;53(3):1087-1098. https://doi.org/10.1039/D3DT03273F, https://doi.org/10.1039/d3dt03273f

Author

Galimova, Milyausha F. ; Zueva, Ekaterina M. ; Petrova, Maria M. ; Dobrynin, Alexey B. ; Kolesnikov, Ilya E. ; Musina, Elvira I. ; Musin, Rustem R. ; Karasik, Andrey A. ; Sinyashin, Oleg G. / Design of luminescent complexes with different Cu4I4 cores based on pyridyl phenoxarsines. In: Dalton Transactions. 2024 ; Vol. 53, No. 3. pp. 1087-1098.

BibTeX

@article{5f5c47ab8d524c669b6f8748f8b99c6a,
title = "Design of luminescent complexes with different Cu4I4 cores based on pyridyl phenoxarsines",
abstract = "A series of luminescent Cu4I4 clusters with stair-step, cubane, and octahedral geometries supported by a novel type of cyclic As,N-ligand, pyridyl-containing 10-phenoxarsines, were synthesized and characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single-crystal X-ray diffraction analysis. An unusual arrangement of As,N-bidentate and μ2-iodo ligands was found in the octahedral cluster. The structural diversity of the Cu(i) complexes is reflected in their photophysical properties: the phosphorescence spectra of the compounds display emission in a broad spectral range of 495-597 nm. The complex with the Cu4I4L2 stoichiometry bearing a stair-step Cu4I4 core demonstrates temperature-dependent dual emission. The luminescence properties of all complexes were rationalized by DFT calculations.",
author = "Galimova, {Milyausha F.} and Zueva, {Ekaterina M.} and Petrova, {Maria M.} and Dobrynin, {Alexey B.} and Kolesnikov, {Ilya E.} and Musina, {Elvira I.} and Musin, {Rustem R.} and Karasik, {Andrey A.} and Sinyashin, {Oleg G.}",
year = "2024",
month = jan,
day = "1",
doi = "10.1039/D3DT03273F",
language = "English",
volume = "53",
pages = "1087--1098",
journal = "Dalton Transactions",
issn = "1477-9226",
publisher = "Royal Society of Chemistry",
number = "3",

}

RIS

TY - JOUR

T1 - Design of luminescent complexes with different Cu4I4 cores based on pyridyl phenoxarsines

AU - Galimova, Milyausha F.

AU - Zueva, Ekaterina M.

AU - Petrova, Maria M.

AU - Dobrynin, Alexey B.

AU - Kolesnikov, Ilya E.

AU - Musina, Elvira I.

AU - Musin, Rustem R.

AU - Karasik, Andrey A.

AU - Sinyashin, Oleg G.

PY - 2024/1/1

Y1 - 2024/1/1

N2 - A series of luminescent Cu4I4 clusters with stair-step, cubane, and octahedral geometries supported by a novel type of cyclic As,N-ligand, pyridyl-containing 10-phenoxarsines, were synthesized and characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single-crystal X-ray diffraction analysis. An unusual arrangement of As,N-bidentate and μ2-iodo ligands was found in the octahedral cluster. The structural diversity of the Cu(i) complexes is reflected in their photophysical properties: the phosphorescence spectra of the compounds display emission in a broad spectral range of 495-597 nm. The complex with the Cu4I4L2 stoichiometry bearing a stair-step Cu4I4 core demonstrates temperature-dependent dual emission. The luminescence properties of all complexes were rationalized by DFT calculations.

AB - A series of luminescent Cu4I4 clusters with stair-step, cubane, and octahedral geometries supported by a novel type of cyclic As,N-ligand, pyridyl-containing 10-phenoxarsines, were synthesized and characterized by NMR spectroscopy, mass spectrometry, elemental analysis, and single-crystal X-ray diffraction analysis. An unusual arrangement of As,N-bidentate and μ2-iodo ligands was found in the octahedral cluster. The structural diversity of the Cu(i) complexes is reflected in their photophysical properties: the phosphorescence spectra of the compounds display emission in a broad spectral range of 495-597 nm. The complex with the Cu4I4L2 stoichiometry bearing a stair-step Cu4I4 core demonstrates temperature-dependent dual emission. The luminescence properties of all complexes were rationalized by DFT calculations.

UR - https://www.mendeley.com/catalogue/06a83535-ab9c-3940-b46e-78f957cb44da/

U2 - 10.1039/D3DT03273F

DO - 10.1039/D3DT03273F

M3 - Article

VL - 53

SP - 1087

EP - 1098

JO - Dalton Transactions

JF - Dalton Transactions

SN - 1477-9226

IS - 3

ER -

ID: 117778129