Delayed Fluorescence of Dyes Sensitized by Eu3+ Chelate Nanoparticles

Leonid Yu Mironov, Peter S. Parfenov, Anna V. Shurukhina, Yaroslav I. Lebedev, Anastasiya A. Metlenko

Research output: Contribution to journalArticlepeer-review

2 Scopus citations

Abstract

Dye-doped nanoparticles of Eu3+ chelate complexes with naphtoyltrifluoroacetone and 1,10-phenanthroline were synthesized using two different reprecipitation techniques. The nanoparticles were characterized by atomic force microscopy, absorption spectroscopy, steady-state, and time-resolved fluorescence spectroscopy. Fluorescent spectroscopy of chelate nanoparticles doped with Oxazine 170 and Nile blue dyes indicates that a single dye molecule efficiently quenches luminescence of more than a hundred chelates. The Eu3+ chelates have a significantly longer luminescence lifetime than organic dyes, which leads to the appearance of delayed dyes fluorescence with microsecond lifetimes. The fluorescence brightness of dye-doped chelate nanoparticles was determined to be 50 times higher than that of a single Rhodamine 6G molecule. The combination of high fluorescence brightness and long fluorescence lifetime of the dye-doped chelate nanoparticles is promising for time-gated applications. (Graph Presented).

Original languageEnglish
Pages (from-to)19958-19965
Number of pages8
JournalJournal of Physical Chemistry C
Volume121
Issue number36
DOIs
StatePublished - 14 Sep 2017

Scopus subject areas

  • Electronic, Optical and Magnetic Materials
  • Energy(all)
  • Physical and Theoretical Chemistry
  • Surfaces, Coatings and Films

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