Cu3(SeO4)2(SeO3OH)2(H2O)16 - The First Example of a Linear Octahedral-Tetrahedral Heptamer in Inorganic Compounds

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5 Citations (Scopus)

Abstract

Cu-3(SeO4)(2)(SeO3OH)(2)(H2O)(16) (1) is a novel copper selenate hydrate and the first inorganic compound to contain linear octahedral-tetrahedral heptamers. The heptamers are formed by successive polymerization of two SeO3OH tetrahedra, two SeO4 tetrahedra, and three Cu(H2O)(4)O-2 octahedra. The linkages between the octahedra and tetrahedra are in the trans-configuration, which is in agreement with the Jahn-Teller distortion of the octahedral coordination geometry of Cu2+.
Original languageEnglish
Pages (from-to)5311-5313
Number of pages3
JournalEuropean Journal of Inorganic Chemistry
Issue number32
DOIs
Publication statusPublished - 2015

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Selenic Acid
Inorganic compounds
Jahn-Teller effect
Hydrates
Copper
Polymerization
Geometry

Cite this

@article{3e0331c398384100ae7527b6922efd52,
title = "Cu3(SeO4)2(SeO3OH)2(H2O)16 - The First Example of a Linear Octahedral-Tetrahedral Heptamer in Inorganic Compounds",
abstract = "Cu-3(SeO4)(2)(SeO3OH)(2)(H2O)(16) (1) is a novel copper selenate hydrate and the first inorganic compound to contain linear octahedral-tetrahedral heptamers. The heptamers are formed by successive polymerization of two SeO3OH tetrahedra, two SeO4 tetrahedra, and three Cu(H2O)(4)O-2 octahedra. The linkages between the octahedra and tetrahedra are in the trans-configuration, which is in agreement with the Jahn-Teller distortion of the octahedral coordination geometry of Cu2+.",
author = "V.V. Gurzhiy and A. Al-Shuray and S.N. Britvin and S.V. Krivovichev",
year = "2015",
doi = "10.1002/ejic.201500927",
language = "English",
pages = "5311--5313",
journal = "European Journal of Inorganic Chemistry",
issn = "1434-1948",
publisher = "Wiley-Blackwell",
number = "32",

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TY - JOUR

T1 - Cu3(SeO4)2(SeO3OH)2(H2O)16 - The First Example of a Linear Octahedral-Tetrahedral Heptamer in Inorganic Compounds

AU - Gurzhiy, V.V.

AU - Al-Shuray, A.

AU - Britvin, S.N.

AU - Krivovichev, S.V.

PY - 2015

Y1 - 2015

N2 - Cu-3(SeO4)(2)(SeO3OH)(2)(H2O)(16) (1) is a novel copper selenate hydrate and the first inorganic compound to contain linear octahedral-tetrahedral heptamers. The heptamers are formed by successive polymerization of two SeO3OH tetrahedra, two SeO4 tetrahedra, and three Cu(H2O)(4)O-2 octahedra. The linkages between the octahedra and tetrahedra are in the trans-configuration, which is in agreement with the Jahn-Teller distortion of the octahedral coordination geometry of Cu2+.

AB - Cu-3(SeO4)(2)(SeO3OH)(2)(H2O)(16) (1) is a novel copper selenate hydrate and the first inorganic compound to contain linear octahedral-tetrahedral heptamers. The heptamers are formed by successive polymerization of two SeO3OH tetrahedra, two SeO4 tetrahedra, and three Cu(H2O)(4)O-2 octahedra. The linkages between the octahedra and tetrahedra are in the trans-configuration, which is in agreement with the Jahn-Teller distortion of the octahedral coordination geometry of Cu2+.

U2 - 10.1002/ejic.201500927

DO - 10.1002/ejic.201500927

M3 - Article

SP - 5311

EP - 5313

JO - European Journal of Inorganic Chemistry

JF - European Journal of Inorganic Chemistry

SN - 1434-1948

IS - 32

ER -