Crystalline borosilicates of alkali and alkaline earth metals: hierarchy, fundamental building blocks and thermal expansion

Research output

Abstract

A brief review is presented of the structure hierarchy, main fundamental building blocks (FBBs) and some thermal characteristics of crystalline alkali and alkaline earth borosilicates. Low-dimensional borosilicate anions are typical for borosilicates with considerable contents of non-tetrahedrally coordinated cations. There are only six types of borosilicate anions containing boron in BO3 triangles, which are almost never connected to silicon tetrahedra. The lower the ratio "non-tetrahedral/tetrahedral cation", the higher the dimension of the layered and framework anions that form. Most Si-dominant borosilicates (B/Si

Original languageEnglish
Pages (from-to)129-139
Number of pages11
JournalEuropean journal of glass science and technology. Part B, Physics and chemistry of glasses
Volume60
Issue number4
DOIs
Publication statusPublished - 4 Aug 2019

Cite this

@article{8cf03207666d4a1f85c8dcf9d50af249,
title = "Crystalline borosilicates of alkali and alkaline earth metals: hierarchy, fundamental building blocks and thermal expansion",
abstract = "A brief review is presented of the structure hierarchy, main fundamental building blocks (FBBs) and some thermal characteristics of crystalline alkali and alkaline earth borosilicates. Low-dimensional borosilicate anions are typical for borosilicates with considerable contents of non-tetrahedrally coordinated cations. There are only six types of borosilicate anions containing boron in BO3 triangles, which are almost never connected to silicon tetrahedra. The lower the ratio {"}non-tetrahedral/tetrahedral cation{"}, the higher the dimension of the layered and framework anions that form. Most Si-dominant borosilicates (B/Si",
keywords = "HYDROTHERMAL SYNTHESIS, STRUCTURAL CHEMISTRY, RIETVELD REFINEMENT, BEHAVIOR, BORATE, SILICOBORATE, REEDMERGNERITE, SILLIMANITE, BOROLEUCITE, TAJIKISTAN",
author = "Krzhizhanovskaya, {Maria G.} and Bubnova, {Rimma S.} and Filatov, {Stanislav K.}",
year = "2019",
month = "8",
day = "4",
doi = "10.13036/17533562.60.4.049",
language = "Английский",
volume = "60",
pages = "129--139",
journal = "European journal of glass science and technology. Part B, Physics and chemistry of glasses",
issn = "1753-3562",
publisher = "Society of Glass Technology",
number = "4",

}

TY - JOUR

T1 - Crystalline borosilicates of alkali and alkaline earth metals: hierarchy, fundamental building blocks and thermal expansion

AU - Krzhizhanovskaya, Maria G.

AU - Bubnova, Rimma S.

AU - Filatov, Stanislav K.

PY - 2019/8/4

Y1 - 2019/8/4

N2 - A brief review is presented of the structure hierarchy, main fundamental building blocks (FBBs) and some thermal characteristics of crystalline alkali and alkaline earth borosilicates. Low-dimensional borosilicate anions are typical for borosilicates with considerable contents of non-tetrahedrally coordinated cations. There are only six types of borosilicate anions containing boron in BO3 triangles, which are almost never connected to silicon tetrahedra. The lower the ratio "non-tetrahedral/tetrahedral cation", the higher the dimension of the layered and framework anions that form. Most Si-dominant borosilicates (B/Si

AB - A brief review is presented of the structure hierarchy, main fundamental building blocks (FBBs) and some thermal characteristics of crystalline alkali and alkaline earth borosilicates. Low-dimensional borosilicate anions are typical for borosilicates with considerable contents of non-tetrahedrally coordinated cations. There are only six types of borosilicate anions containing boron in BO3 triangles, which are almost never connected to silicon tetrahedra. The lower the ratio "non-tetrahedral/tetrahedral cation", the higher the dimension of the layered and framework anions that form. Most Si-dominant borosilicates (B/Si

KW - HYDROTHERMAL SYNTHESIS

KW - STRUCTURAL CHEMISTRY

KW - RIETVELD REFINEMENT

KW - BEHAVIOR

KW - BORATE

KW - SILICOBORATE

KW - REEDMERGNERITE

KW - SILLIMANITE

KW - BOROLEUCITE

KW - TAJIKISTAN

UR - http://www.mendeley.com/research/crystalline-borosilicates-alkali-alkaline-earth-metals-hierarchy-fundamental-building-blocks-thermal

U2 - 10.13036/17533562.60.4.049

DO - 10.13036/17533562.60.4.049

M3 - статья

VL - 60

SP - 129

EP - 139

JO - European journal of glass science and technology. Part B, Physics and chemistry of glasses

JF - European journal of glass science and technology. Part B, Physics and chemistry of glasses

SN - 1753-3562

IS - 4

ER -