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Crystal Structure of a High-Temperature Modification of Cs2SO4. / Shablinskii, A. P.; Biryukov, Ya. P.; Krzhizhanovskaya, M. G.; Bubnova, R. S.; Filatov, S. K.

In: Glass Physics and Chemistry, Vol. 51, No. 2, 05.08.2025, p. 217-222.

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@article{71e26148a5b04f73ab398a2b40c38e93,
title = "Crystal Structure of a High-Temperature Modification of Cs2SO4",
abstract = "Abstract: This article presents the results of the refinement of the crystal structure of α-Cs2SO4 at a temperature of 800°C in the edge and apex models. The arrangement of the oxygen atoms{\textquoteright} sites, which are not fixed by symmetry, unlike the Cs and S sites, is clarified. It is proposed that the edge model better corresponds to the experimental data and satisfies the crystallochemical parameters. However, the bond lengths in the apex model are in better agreement with the published data.",
keywords = "crystal structure, disorder, polymorphism, sulfates",
author = "Shablinskii, {A. P.} and Biryukov, {Ya. P.} and Krzhizhanovskaya, {M. G.} and Bubnova, {R. S.} and Filatov, {S. K.}",
year = "2025",
month = aug,
day = "5",
doi = "10.1134/s1087659625600255",
language = "English",
volume = "51",
pages = "217--222",
journal = "Glass Physics and Chemistry",
issn = "1087-6596",
publisher = "МАИК {"}Наука/Интерпериодика{"}",
number = "2",

}

RIS

TY - JOUR

T1 - Crystal Structure of a High-Temperature Modification of Cs2SO4

AU - Shablinskii, A. P.

AU - Biryukov, Ya. P.

AU - Krzhizhanovskaya, M. G.

AU - Bubnova, R. S.

AU - Filatov, S. K.

PY - 2025/8/5

Y1 - 2025/8/5

N2 - Abstract: This article presents the results of the refinement of the crystal structure of α-Cs2SO4 at a temperature of 800°C in the edge and apex models. The arrangement of the oxygen atoms’ sites, which are not fixed by symmetry, unlike the Cs and S sites, is clarified. It is proposed that the edge model better corresponds to the experimental data and satisfies the crystallochemical parameters. However, the bond lengths in the apex model are in better agreement with the published data.

AB - Abstract: This article presents the results of the refinement of the crystal structure of α-Cs2SO4 at a temperature of 800°C in the edge and apex models. The arrangement of the oxygen atoms’ sites, which are not fixed by symmetry, unlike the Cs and S sites, is clarified. It is proposed that the edge model better corresponds to the experimental data and satisfies the crystallochemical parameters. However, the bond lengths in the apex model are in better agreement with the published data.

KW - crystal structure

KW - disorder

KW - polymorphism

KW - sulfates

UR - https://www.mendeley.com/catalogue/e753fa92-4beb-3f51-a440-8bd0ccd229ef/

U2 - 10.1134/s1087659625600255

DO - 10.1134/s1087659625600255

M3 - Article

VL - 51

SP - 217

EP - 222

JO - Glass Physics and Chemistry

JF - Glass Physics and Chemistry

SN - 1087-6596

IS - 2

ER -

ID: 141438910