Research output: Contribution to journal › Article › peer-review
Crystal Structure of a High-Temperature Modification of Cs2SO4. / Shablinskii, A. P.; Biryukov, Ya. P.; Krzhizhanovskaya, M. G.; Bubnova, R. S.; Filatov, S. K.
In: Glass Physics and Chemistry, Vol. 51, No. 2, 05.08.2025, p. 217-222.Research output: Contribution to journal › Article › peer-review
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TY - JOUR
T1 - Crystal Structure of a High-Temperature Modification of Cs2SO4
AU - Shablinskii, A. P.
AU - Biryukov, Ya. P.
AU - Krzhizhanovskaya, M. G.
AU - Bubnova, R. S.
AU - Filatov, S. K.
PY - 2025/8/5
Y1 - 2025/8/5
N2 - Abstract: This article presents the results of the refinement of the crystal structure of α-Cs2SO4 at a temperature of 800°C in the edge and apex models. The arrangement of the oxygen atoms’ sites, which are not fixed by symmetry, unlike the Cs and S sites, is clarified. It is proposed that the edge model better corresponds to the experimental data and satisfies the crystallochemical parameters. However, the bond lengths in the apex model are in better agreement with the published data.
AB - Abstract: This article presents the results of the refinement of the crystal structure of α-Cs2SO4 at a temperature of 800°C in the edge and apex models. The arrangement of the oxygen atoms’ sites, which are not fixed by symmetry, unlike the Cs and S sites, is clarified. It is proposed that the edge model better corresponds to the experimental data and satisfies the crystallochemical parameters. However, the bond lengths in the apex model are in better agreement with the published data.
KW - crystal structure
KW - disorder
KW - polymorphism
KW - sulfates
UR - https://www.mendeley.com/catalogue/e753fa92-4beb-3f51-a440-8bd0ccd229ef/
U2 - 10.1134/s1087659625600255
DO - 10.1134/s1087659625600255
M3 - Article
VL - 51
SP - 217
EP - 222
JO - Glass Physics and Chemistry
JF - Glass Physics and Chemistry
SN - 1087-6596
IS - 2
ER -
ID: 141438910