Crystal chemistry of inorganic compounds based on chains of oxocentered tetrahedra I. Crystal structure of chloromenite, Cu9O2(SeO3)4Cl6

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Abstract

The crystal structure of chloromenite, Cu9O2(SeO3)4Cl6, a = 14.170(3) Å, b = 6.262(1) Å, c = 12.999(3) Å, β = 113.05(1)°, V = 1061.3(4) Å3, Z = 2, space group 12/m, has been solved by direct methods and refined to an R(F) index of 0.051 (wR(F2) = 0.128). The structure is based on unbranched zweier single chains {uB, l1∞}[O2Cu6] of corner sharing [OCu4] tetrahedra running parallel to the b axis. The geometry of structurally similar {uB, l1∞}[O2M6] (M = Cu, Zn) chains of oxocentered [OM4] tetrahedra (M = Cu, Zn) in inorganic compounds is discussed.

Original languageEnglish
Pages (from-to)645-649
Number of pages5
JournalZeitschrift fur Kristallographie - New Crystal Structures
Volume213
Issue number12
DOIs
Publication statusPublished - 1 Jan 1998

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Crystal chemistry
Inorganic compounds
inorganic compounds
tetrahedrons
Crystal structure
chemistry
crystal structure
Geometry
crystals
geometry

Scopus subject areas

  • Materials Science(all)
  • Condensed Matter Physics
  • Inorganic Chemistry

Cite this

@article{8270cc84a82c45948efbacc17dd5e24b,
title = "Crystal chemistry of inorganic compounds based on chains of oxocentered tetrahedra I. Crystal structure of chloromenite, Cu9O2(SeO3)4Cl6",
abstract = "The crystal structure of chloromenite, Cu9O2(SeO3)4Cl6, a = 14.170(3) {\AA}, b = 6.262(1) {\AA}, c = 12.999(3) {\AA}, β = 113.05(1)°, V = 1061.3(4) {\AA}3, Z = 2, space group 12/m, has been solved by direct methods and refined to an R(F) index of 0.051 (wR(F2) = 0.128). The structure is based on unbranched zweier single chains {uB, l1∞}[O2Cu6] of corner sharing [OCu4] tetrahedra running parallel to the b axis. The geometry of structurally similar {uB, l1∞}[O2M6] (M = Cu, Zn) chains of oxocentered [OM4] tetrahedra (M = Cu, Zn) in inorganic compounds is discussed.",
author = "Krivovichev, {S. V.} and Filatov, {S. K.} and Semenova, {T. F.} and Rozhdestvenskaya, {I. V.}",
year = "1998",
month = "1",
day = "1",
doi = "10.1524/zkri.1998.213.12.645",
language = "English",
volume = "213",
pages = "645--649",
journal = "Zeitschrift für Kristallographie. New crystal structures",
issn = "1433-7266",
publisher = "De Gruyter",
number = "12",

}

TY - JOUR

T1 - Crystal chemistry of inorganic compounds based on chains of oxocentered tetrahedra I. Crystal structure of chloromenite, Cu9O2(SeO3)4Cl6

AU - Krivovichev, S. V.

AU - Filatov, S. K.

AU - Semenova, T. F.

AU - Rozhdestvenskaya, I. V.

PY - 1998/1/1

Y1 - 1998/1/1

N2 - The crystal structure of chloromenite, Cu9O2(SeO3)4Cl6, a = 14.170(3) Å, b = 6.262(1) Å, c = 12.999(3) Å, β = 113.05(1)°, V = 1061.3(4) Å3, Z = 2, space group 12/m, has been solved by direct methods and refined to an R(F) index of 0.051 (wR(F2) = 0.128). The structure is based on unbranched zweier single chains {uB, l1∞}[O2Cu6] of corner sharing [OCu4] tetrahedra running parallel to the b axis. The geometry of structurally similar {uB, l1∞}[O2M6] (M = Cu, Zn) chains of oxocentered [OM4] tetrahedra (M = Cu, Zn) in inorganic compounds is discussed.

AB - The crystal structure of chloromenite, Cu9O2(SeO3)4Cl6, a = 14.170(3) Å, b = 6.262(1) Å, c = 12.999(3) Å, β = 113.05(1)°, V = 1061.3(4) Å3, Z = 2, space group 12/m, has been solved by direct methods and refined to an R(F) index of 0.051 (wR(F2) = 0.128). The structure is based on unbranched zweier single chains {uB, l1∞}[O2Cu6] of corner sharing [OCu4] tetrahedra running parallel to the b axis. The geometry of structurally similar {uB, l1∞}[O2M6] (M = Cu, Zn) chains of oxocentered [OM4] tetrahedra (M = Cu, Zn) in inorganic compounds is discussed.

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U2 - 10.1524/zkri.1998.213.12.645

DO - 10.1524/zkri.1998.213.12.645

M3 - Article

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VL - 213

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JO - Zeitschrift für Kristallographie. New crystal structures

JF - Zeitschrift für Kristallographie. New crystal structures

SN - 1433-7266

IS - 12

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